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Hexaaquamagnesium(II) bis{[2-(1-phenyl-1H-tetrazol-5-yl)sulfanyl]acetate}
The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(7)N(4)O(2)S)(2), contains one-half of a [Mg(H(2)O)(6)](2+) cation ([Image: see text] symmetry) and one uncoordinated 2-[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]acetate anion. The Mg(II) cation is coordinated by six water molecules, exhib...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979576/ https://www.ncbi.nlm.nih.gov/pubmed/21579302 http://dx.doi.org/10.1107/S1600536810016983 |
Sumario: | The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(7)N(4)O(2)S)(2), contains one-half of a [Mg(H(2)O)(6)](2+) cation ([Image: see text] symmetry) and one uncoordinated 2-[(1-phenyl-1H-tetrazol-5-yl)sulfanyl]acetate anion. The Mg(II) cation is coordinated by six water molecules, exhibiting a slightly distorted octahedral coordination. A two-dimensional network parallel to (001) is formed via extensive hydrogen-bonding interactions involving the water molecules as donors and the tetrazole N and carboxylate O atoms of the anion as acceptors. The shortest distance between two adjacent parallel benzene rings is 3.315 (2) Å. The dihedral angle between the benzene ring and the tetrazole ring is 40.98 (2)°. |
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