Hexaaqua­magnesium(II) bis­{[2-(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate}

The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(7)N(4)O(2)S)(2), contains one-half of a [Mg(H(2)O)(6)](2+) cation ([Image: see text] symmetry) and one uncoordinated 2-[(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate anion. The Mg(II) cation is coordinated by six water mol­ecules, exhib...

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Detalles Bibliográficos
Autores principales: Fu, Chun-Hua, Zhou, Xiang, Yu, Qing, Bian, He-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979576/
https://www.ncbi.nlm.nih.gov/pubmed/21579302
http://dx.doi.org/10.1107/S1600536810016983
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author Fu, Chun-Hua
Zhou, Xiang
Yu, Qing
Bian, He-Dong
author_facet Fu, Chun-Hua
Zhou, Xiang
Yu, Qing
Bian, He-Dong
author_sort Fu, Chun-Hua
collection PubMed
description The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(7)N(4)O(2)S)(2), contains one-half of a [Mg(H(2)O)(6)](2+) cation ([Image: see text] symmetry) and one uncoordinated 2-[(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate anion. The Mg(II) cation is coordinated by six water mol­ecules, exhibiting a slightly distorted octa­hedral coordination. A two-dimensional network parallel to (001) is formed via extensive hydrogen-bonding inter­actions involving the water mol­ecules as donors and the tetra­zole N and carboxyl­ate O atoms of the anion as acceptors. The shortest distance between two adjacent parallel benzene rings is 3.315 (2) Å. The dihedral angle between the benzene ring and the tetra­zole ring is 40.98 (2)°.
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spelling pubmed-29795762010-12-30 Hexaaqua­magnesium(II) bis­{[2-(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate} Fu, Chun-Hua Zhou, Xiang Yu, Qing Bian, He-Dong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Mg(H(2)O)(6)](C(9)H(7)N(4)O(2)S)(2), contains one-half of a [Mg(H(2)O)(6)](2+) cation ([Image: see text] symmetry) and one uncoordinated 2-[(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate anion. The Mg(II) cation is coordinated by six water mol­ecules, exhibiting a slightly distorted octa­hedral coordination. A two-dimensional network parallel to (001) is formed via extensive hydrogen-bonding inter­actions involving the water mol­ecules as donors and the tetra­zole N and carboxyl­ate O atoms of the anion as acceptors. The shortest distance between two adjacent parallel benzene rings is 3.315 (2) Å. The dihedral angle between the benzene ring and the tetra­zole ring is 40.98 (2)°. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979576/ /pubmed/21579302 http://dx.doi.org/10.1107/S1600536810016983 Text en © Fu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Fu, Chun-Hua
Zhou, Xiang
Yu, Qing
Bian, He-Dong
Hexaaqua­magnesium(II) bis­{[2-(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate}
title Hexaaqua­magnesium(II) bis­{[2-(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate}
title_full Hexaaqua­magnesium(II) bis­{[2-(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate}
title_fullStr Hexaaqua­magnesium(II) bis­{[2-(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate}
title_full_unstemmed Hexaaqua­magnesium(II) bis­{[2-(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate}
title_short Hexaaqua­magnesium(II) bis­{[2-(1-phenyl-1H-tetra­zol-5-yl)sulfan­yl]acetate}
title_sort hexaaqua­magnesium(ii) bis­{[2-(1-phenyl-1h-tetra­zol-5-yl)sulfan­yl]acetate}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979576/
https://www.ncbi.nlm.nih.gov/pubmed/21579302
http://dx.doi.org/10.1107/S1600536810016983
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AT zhouxiang hexaaquamagnesiumiibis21phenyl1htetrazol5ylsulfanylacetate
AT yuqing hexaaquamagnesiumiibis21phenyl1htetrazol5ylsulfanylacetate
AT bianhedong hexaaquamagnesiumiibis21phenyl1htetrazol5ylsulfanylacetate

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