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Bis{2-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]-5-methoxy­phenolato}copper(II) bis­(perchlorate)

In the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Cu(II) atom in the complex dication is chelated by two phenolate O atoms and two imine N atoms from two zwitterionic 2-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]-5-methoxy­phenolate ligands, forming a distorted square-planar geometry...

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Detalles Bibliográficos
Autores principales: Wang, Chen-Yi, Cao, Feng, Wang, Ping, Wu, Xiang, Yuan, Cai-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979578/
https://www.ncbi.nlm.nih.gov/pubmed/21579312
http://dx.doi.org/10.1107/S1600536810017472
Descripción
Sumario:In the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Cu(II) atom in the complex dication is chelated by two phenolate O atoms and two imine N atoms from two zwitterionic 2-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]-5-methoxy­phenolate ligands, forming a distorted square-planar geometry. One of the perchlorate anions is disordered over two sites with occupancies of 0.611 (15) and 0.389 (15). Intra­molecular N—H⋯O hydrogen bonds are observed in the complex dication. In the crystal structure, the perchlorate anions are linked to complex dications by inter­molecular N—H⋯O hydrogen bonds.