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Bis{2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolato}copper(II) bis(perchlorate)
In the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Cu(II) atom in the complex dication is chelated by two phenolate O atoms and two imine N atoms from two zwitterionic 2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolate ligands, forming a distorted square-planar geometry...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979578/ https://www.ncbi.nlm.nih.gov/pubmed/21579312 http://dx.doi.org/10.1107/S1600536810017472 |
| _version_ | 1782191446581837824 |
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| author | Wang, Chen-Yi Cao, Feng Wang, Ping Wu, Xiang Yuan, Cai-Jun |
| author_facet | Wang, Chen-Yi Cao, Feng Wang, Ping Wu, Xiang Yuan, Cai-Jun |
| author_sort | Wang, Chen-Yi |
| collection | PubMed |
| description | In the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Cu(II) atom in the complex dication is chelated by two phenolate O atoms and two imine N atoms from two zwitterionic 2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolate ligands, forming a distorted square-planar geometry. One of the perchlorate anions is disordered over two sites with occupancies of 0.611 (15) and 0.389 (15). Intramolecular N—H⋯O hydrogen bonds are observed in the complex dication. In the crystal structure, the perchlorate anions are linked to complex dications by intermolecular N—H⋯O hydrogen bonds. |
| format | Text |
| id | pubmed-2979578 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29795782010-12-30 Bis{2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolato}copper(II) bis(perchlorate) Wang, Chen-Yi Cao, Feng Wang, Ping Wu, Xiang Yuan, Cai-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(13)H(20)N(2)O(2))(2)](ClO(4))(2), the Cu(II) atom in the complex dication is chelated by two phenolate O atoms and two imine N atoms from two zwitterionic 2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolate ligands, forming a distorted square-planar geometry. One of the perchlorate anions is disordered over two sites with occupancies of 0.611 (15) and 0.389 (15). Intramolecular N—H⋯O hydrogen bonds are observed in the complex dication. In the crystal structure, the perchlorate anions are linked to complex dications by intermolecular N—H⋯O hydrogen bonds. International Union of Crystallography 2010-05-19 /pmc/articles/PMC2979578/ /pubmed/21579312 http://dx.doi.org/10.1107/S1600536810017472 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wang, Chen-Yi Cao, Feng Wang, Ping Wu, Xiang Yuan, Cai-Jun Bis{2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolato}copper(II) bis(perchlorate) |
| title | Bis{2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolato}copper(II) bis(perchlorate) |
| title_full | Bis{2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolato}copper(II) bis(perchlorate) |
| title_fullStr | Bis{2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolato}copper(II) bis(perchlorate) |
| title_full_unstemmed | Bis{2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolato}copper(II) bis(perchlorate) |
| title_short | Bis{2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolato}copper(II) bis(perchlorate) |
| title_sort | bis{2-[2-(isopropylammonio)ethyliminomethyl]-5-methoxyphenolato}copper(ii) bis(perchlorate) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979578/ https://www.ncbi.nlm.nih.gov/pubmed/21579312 http://dx.doi.org/10.1107/S1600536810017472 |
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