Poly[bis­(N,N-dimethyl­formamide-κO)(μ(4)-naphthalene-1,5-disulfonato)magnesium(II)]

The structure of the title compound, [Mg(C(10)H(6)O(6)S(2))(C(3)H(7)NO)(2)](n), consists of MgO(6) octa­hedra ([Image: see text] symmetry) connected to naphthalene-1,5-disulfonate ligands ([Image: see text] symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (...

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Detalles Bibliográficos
Autores principales: Borkowski, Lauren A., Banerjee, Debasis, Parise, John B.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979591/
https://www.ncbi.nlm.nih.gov/pubmed/21579330
http://dx.doi.org/10.1107/S1600536810017952
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author Borkowski, Lauren A.
Banerjee, Debasis
Parise, John B.
author_facet Borkowski, Lauren A.
Banerjee, Debasis
Parise, John B.
author_sort Borkowski, Lauren A.
collection PubMed
description The structure of the title compound, [Mg(C(10)H(6)O(6)S(2))(C(3)H(7)NO)(2)](n), consists of MgO(6) octa­hedra ([Image: see text] symmetry) connected to naphthalene-1,5-disulfonate ligands ([Image: see text] symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethyl­formamide (DMF) mol­ecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg(2+) atom. Disorder over two positions was found in the DMF mol­ecule in a 0.518 (8):0.482 (8) ratio.
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spelling pubmed-29795912010-12-30 Poly[bis­(N,N-dimethyl­formamide-κO)(μ(4)-naphthalene-1,5-disulfonato)magnesium(II)] Borkowski, Lauren A. Banerjee, Debasis Parise, John B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Mg(C(10)H(6)O(6)S(2))(C(3)H(7)NO)(2)](n), consists of MgO(6) octa­hedra ([Image: see text] symmetry) connected to naphthalene-1,5-disulfonate ligands ([Image: see text] symmetry) in the equatoral plane, forming a two-dimensional network propagating parallel to (010). The coordination sphere of the Mg atom is completed by the O atoms of two N,N-dimethyl­formamide (DMF) mol­ecules in the axial positions. The title compound represents the first time the naphthalene-1,5-disulfonate anion is bound directly to a Mg(2+) atom. Disorder over two positions was found in the DMF mol­ecule in a 0.518 (8):0.482 (8) ratio. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979591/ /pubmed/21579330 http://dx.doi.org/10.1107/S1600536810017952 Text en © Borkowski et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Borkowski, Lauren A.
Banerjee, Debasis
Parise, John B.
Poly[bis­(N,N-dimethyl­formamide-κO)(μ(4)-naphthalene-1,5-disulfonato)magnesium(II)]
title Poly[bis­(N,N-dimethyl­formamide-κO)(μ(4)-naphthalene-1,5-disulfonato)magnesium(II)]
title_full Poly[bis­(N,N-dimethyl­formamide-κO)(μ(4)-naphthalene-1,5-disulfonato)magnesium(II)]
title_fullStr Poly[bis­(N,N-dimethyl­formamide-κO)(μ(4)-naphthalene-1,5-disulfonato)magnesium(II)]
title_full_unstemmed Poly[bis­(N,N-dimethyl­formamide-κO)(μ(4)-naphthalene-1,5-disulfonato)magnesium(II)]
title_short Poly[bis­(N,N-dimethyl­formamide-κO)(μ(4)-naphthalene-1,5-disulfonato)magnesium(II)]
title_sort poly[bis­(n,n-dimethyl­formamide-κo)(μ(4)-naphthalene-1,5-disulfonato)magnesium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979591/
https://www.ncbi.nlm.nih.gov/pubmed/21579330
http://dx.doi.org/10.1107/S1600536810017952
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AT parisejohnb polybisnndimethylformamidekom4naphthalene15disulfonatomagnesiumii

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