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Ferrocene-1-carbaldehyde thio­semi­carbazone

The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)N(3)S)], consists of two crystallographically independent mol­ecules, A and B. The cyclo­penta­dienyl (Cp) rings in both mol­ecules adopt an eclipsed conformation and are parallel to each other, forming dihedral angles of 2.5 (3) and 1...

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Detalles Bibliográficos
Autores principales: Vikneswaran, M. R., Teoh, Siang Guan, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979593/
https://www.ncbi.nlm.nih.gov/pubmed/21579319
http://dx.doi.org/10.1107/S1600536810017605
Descripción
Sumario:The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)N(3)S)], consists of two crystallographically independent mol­ecules, A and B. The cyclo­penta­dienyl (Cp) rings in both mol­ecules adopt an eclipsed conformation and are parallel to each other, forming dihedral angles of 2.5 (3) and 1.1 (3)°, respectively. The mean plane of the semicarbazone group is coplanar with the attached Cp ring in mol­ecule A, whereas it is twisted away in mol­ecule B. In the crystal structure, inter­molecular N—H⋯S hydrogen bonds link the mol­ecules into two-dimensional planes parallel to the ab plane. The structure is further consolidated by C—H⋯π inter­actions.