Ferrocene-1-carbaldehyde thio­semi­carbazone

The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)N(3)S)], consists of two crystallographically independent mol­ecules, A and B. The cyclo­penta­dienyl (Cp) rings in both mol­ecules adopt an eclipsed conformation and are parallel to each other, forming dihedral angles of 2.5 (3) and 1...

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Detalles Bibliográficos
Autores principales: Vikneswaran, M. R., Teoh, Siang Guan, Yeap, Chin Sing, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979593/
https://www.ncbi.nlm.nih.gov/pubmed/21579319
http://dx.doi.org/10.1107/S1600536810017605
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author Vikneswaran, M. R.
Teoh, Siang Guan
Yeap, Chin Sing
Fun, Hoong-Kun
author_facet Vikneswaran, M. R.
Teoh, Siang Guan
Yeap, Chin Sing
Fun, Hoong-Kun
author_sort Vikneswaran, M. R.
collection PubMed
description The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)N(3)S)], consists of two crystallographically independent mol­ecules, A and B. The cyclo­penta­dienyl (Cp) rings in both mol­ecules adopt an eclipsed conformation and are parallel to each other, forming dihedral angles of 2.5 (3) and 1.1 (3)°, respectively. The mean plane of the semicarbazone group is coplanar with the attached Cp ring in mol­ecule A, whereas it is twisted away in mol­ecule B. In the crystal structure, inter­molecular N—H⋯S hydrogen bonds link the mol­ecules into two-dimensional planes parallel to the ab plane. The structure is further consolidated by C—H⋯π inter­actions.
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spelling pubmed-29795932010-12-30 Ferrocene-1-carbaldehyde thio­semi­carbazone Vikneswaran, M. R. Teoh, Siang Guan Yeap, Chin Sing Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)N(3)S)], consists of two crystallographically independent mol­ecules, A and B. The cyclo­penta­dienyl (Cp) rings in both mol­ecules adopt an eclipsed conformation and are parallel to each other, forming dihedral angles of 2.5 (3) and 1.1 (3)°, respectively. The mean plane of the semicarbazone group is coplanar with the attached Cp ring in mol­ecule A, whereas it is twisted away in mol­ecule B. In the crystal structure, inter­molecular N—H⋯S hydrogen bonds link the mol­ecules into two-dimensional planes parallel to the ab plane. The structure is further consolidated by C—H⋯π inter­actions. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979593/ /pubmed/21579319 http://dx.doi.org/10.1107/S1600536810017605 Text en © Vikneswaran et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Vikneswaran, M. R.
Teoh, Siang Guan
Yeap, Chin Sing
Fun, Hoong-Kun
Ferrocene-1-carbaldehyde thio­semi­carbazone
title Ferrocene-1-carbaldehyde thio­semi­carbazone
title_full Ferrocene-1-carbaldehyde thio­semi­carbazone
title_fullStr Ferrocene-1-carbaldehyde thio­semi­carbazone
title_full_unstemmed Ferrocene-1-carbaldehyde thio­semi­carbazone
title_short Ferrocene-1-carbaldehyde thio­semi­carbazone
title_sort ferrocene-1-carbaldehyde thio­semi­carbazone
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979593/
https://www.ncbi.nlm.nih.gov/pubmed/21579319
http://dx.doi.org/10.1107/S1600536810017605
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AT yeapchinsing ferrocene1carbaldehydethiosemicarbazone
AT funhoongkun ferrocene1carbaldehydethiosemicarbazone

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