Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(II)]

In the centrosymmetric dinuclear mol­ecule of the title compound, [Cd(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Cd(2+) ion is coordinated by three O atoms from two different diphenyl­dicarboxyl­ate (dpa) ligands (one O,O′-bidentate and one monodentate), a chelating bipyridine ligand and...

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Detalles Bibliográficos
Autores principales: Lin, Pei-Xi, Cheng, Yan, Mai, Yu-Lian, An, Zhe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979598/
https://www.ncbi.nlm.nih.gov/pubmed/21579290
http://dx.doi.org/10.1107/S1600536810016387
Descripción
Sumario:In the centrosymmetric dinuclear mol­ecule of the title compound, [Cd(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Cd(2+) ion is coordinated by three O atoms from two different diphenyl­dicarboxyl­ate (dpa) ligands (one O,O′-bidentate and one monodentate), a chelating bipyridine ligand and a water mol­ecule, generating an extremely distorted trigonal-prismatic (or irregular) CdN(2)O(4) coordination geometry for the metal ion. The bridging ligands generate an 18-membered ring, which is stabilized by two pairs of intra­molecular O—H⋯O hydrogen bonds.

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