Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(II)]

In the centrosymmetric dinuclear mol­ecule of the title compound, [Cd(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Cd(2+) ion is coordinated by three O atoms from two different diphenyl­dicarboxyl­ate (dpa) ligands (one O,O′-bidentate and one monodentate), a chelating bipyridine ligand and...

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Detalles Bibliográficos
Autores principales: Lin, Pei-Xi, Cheng, Yan, Mai, Yu-Lian, An, Zhe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979598/
https://www.ncbi.nlm.nih.gov/pubmed/21579290
http://dx.doi.org/10.1107/S1600536810016387
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author Lin, Pei-Xi
Cheng, Yan
Mai, Yu-Lian
An, Zhe
author_facet Lin, Pei-Xi
Cheng, Yan
Mai, Yu-Lian
An, Zhe
author_sort Lin, Pei-Xi
collection PubMed
description In the centrosymmetric dinuclear mol­ecule of the title compound, [Cd(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Cd(2+) ion is coordinated by three O atoms from two different diphenyl­dicarboxyl­ate (dpa) ligands (one O,O′-bidentate and one monodentate), a chelating bipyridine ligand and a water mol­ecule, generating an extremely distorted trigonal-prismatic (or irregular) CdN(2)O(4) coordination geometry for the metal ion. The bridging ligands generate an 18-membered ring, which is stabilized by two pairs of intra­molecular O—H⋯O hydrogen bonds.
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spelling pubmed-29795982010-12-30 Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(II)] Lin, Pei-Xi Cheng, Yan Mai, Yu-Lian An, Zhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric dinuclear mol­ecule of the title compound, [Cd(2)(C(14)H(8)O(4))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], the Cd(2+) ion is coordinated by three O atoms from two different diphenyl­dicarboxyl­ate (dpa) ligands (one O,O′-bidentate and one monodentate), a chelating bipyridine ligand and a water mol­ecule, generating an extremely distorted trigonal-prismatic (or irregular) CdN(2)O(4) coordination geometry for the metal ion. The bridging ligands generate an 18-membered ring, which is stabilized by two pairs of intra­molecular O—H⋯O hydrogen bonds. International Union of Crystallography 2010-05-12 /pmc/articles/PMC2979598/ /pubmed/21579290 http://dx.doi.org/10.1107/S1600536810016387 Text en © Lin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Pei-Xi
Cheng, Yan
Mai, Yu-Lian
An, Zhe
Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(II)]
title Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(II)]
title_full Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(II)]
title_fullStr Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(II)]
title_full_unstemmed Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(II)]
title_short Bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(II)]
title_sort bis(μ-biphenyl-2,2′-dicarboxyl­ato)bis­[aqua­(2,2′-bipyridine)cadmium(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979598/
https://www.ncbi.nlm.nih.gov/pubmed/21579290
http://dx.doi.org/10.1107/S1600536810016387
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