catena-Poly[[bis­(ethyl­enediamine)copper(II)]-μ-sulfato]

In the title compound, [Cu(SO(4))(C(2)H(8)N(2))(2)](n), the Cu, S and two O atoms lie on a mirror plane. The Cu atom is in a distorted octa­hedral environment and the ethyl­enediamine ligand is in a gauche conformation. The sulfate dianion is bridging, forming a one-dimensional chain. A two-dimensio...

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Detalles Bibliográficos
Autores principales: Lutz, Martin, Smeets, Stef, Parois, Pascal
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979599/
https://www.ncbi.nlm.nih.gov/pubmed/21579313
http://dx.doi.org/10.1107/S160053681001737X
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author Lutz, Martin
Smeets, Stef
Parois, Pascal
author_facet Lutz, Martin
Smeets, Stef
Parois, Pascal
author_sort Lutz, Martin
collection PubMed
description In the title compound, [Cu(SO(4))(C(2)H(8)N(2))(2)](n), the Cu, S and two O atoms lie on a mirror plane. The Cu atom is in a distorted octa­hedral environment and the ethyl­enediamine ligand is in a gauche conformation. The sulfate dianion is bridging, forming a one-dimensional chain. A two-dimensional net parallel to (001) is generated by N—H⋯O hydrogen bonding between the chains.
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spelling pubmed-29795992010-12-30 catena-Poly[[bis­(ethyl­enediamine)copper(II)]-μ-sulfato] Lutz, Martin Smeets, Stef Parois, Pascal Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(SO(4))(C(2)H(8)N(2))(2)](n), the Cu, S and two O atoms lie on a mirror plane. The Cu atom is in a distorted octa­hedral environment and the ethyl­enediamine ligand is in a gauche conformation. The sulfate dianion is bridging, forming a one-dimensional chain. A two-dimensional net parallel to (001) is generated by N—H⋯O hydrogen bonding between the chains. International Union of Crystallography 2010-05-19 /pmc/articles/PMC2979599/ /pubmed/21579313 http://dx.doi.org/10.1107/S160053681001737X Text en © Lutz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lutz, Martin
Smeets, Stef
Parois, Pascal
catena-Poly[[bis­(ethyl­enediamine)copper(II)]-μ-sulfato]
title catena-Poly[[bis­(ethyl­enediamine)copper(II)]-μ-sulfato]
title_full catena-Poly[[bis­(ethyl­enediamine)copper(II)]-μ-sulfato]
title_fullStr catena-Poly[[bis­(ethyl­enediamine)copper(II)]-μ-sulfato]
title_full_unstemmed catena-Poly[[bis­(ethyl­enediamine)copper(II)]-μ-sulfato]
title_short catena-Poly[[bis­(ethyl­enediamine)copper(II)]-μ-sulfato]
title_sort catena-poly[[bis­(ethyl­enediamine)copper(ii)]-μ-sulfato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979599/
https://www.ncbi.nlm.nih.gov/pubmed/21579313
http://dx.doi.org/10.1107/S160053681001737X
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AT paroispascal catenapolybisethylenediaminecopperiimsulfato

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