Tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(III)

The title compound, [Bi(C(8)H(18)PS(2))(3)], contains a Bi(III) cation surrounded by three bis­(2-methyl­prop­yl)dithio­phosphinate anions, leading to a distorted octa­hedral coordination for the heavy metal. The Bi—S and S—P bond lengths are in the ranges 2.7694 (18)–2.8391 (17) and 2.019 (2)–2.035...

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Detalles Bibliográficos
Autores principales: Shad, Hazoor A., Malik, M. Azad, Tahir, M. Nawaz, Chohan, Zahid H., Thebo, Khalid H., Helliwell, Madeleine
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979605/
https://www.ncbi.nlm.nih.gov/pubmed/21579267
http://dx.doi.org/10.1107/S1600536810015618
Descripción
Sumario:The title compound, [Bi(C(8)H(18)PS(2))(3)], contains a Bi(III) cation surrounded by three bis­(2-methyl­prop­yl)dithio­phosphinate anions, leading to a distorted octa­hedral coordination for the heavy metal. The Bi—S and S—P bond lengths are in the ranges 2.7694 (18)–2.8391 (17) and 2.019 (2)–2.035 (2) Å, respectively. The crystal structure is consolidated by C—H⋯S hydrogen bonds. Intra­molecular C—H⋯π inter­actions also play a role in stabilizing the mol­ecules.

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