Tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(III)

The title compound, [Bi(C(8)H(18)PS(2))(3)], contains a Bi(III) cation surrounded by three bis­(2-methyl­prop­yl)dithio­phosphinate anions, leading to a distorted octa­hedral coordination for the heavy metal. The Bi—S and S—P bond lengths are in the ranges 2.7694 (18)–2.8391 (17) and 2.019 (2)–2.035...

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Detalles Bibliográficos
Autores principales: Shad, Hazoor A., Malik, M. Azad, Tahir, M. Nawaz, Chohan, Zahid H., Thebo, Khalid H., Helliwell, Madeleine
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979605/
https://www.ncbi.nlm.nih.gov/pubmed/21579267
http://dx.doi.org/10.1107/S1600536810015618
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author Shad, Hazoor A.
Malik, M. Azad
Tahir, M. Nawaz
Chohan, Zahid H.
Thebo, Khalid H.
Helliwell, Madeleine
author_facet Shad, Hazoor A.
Malik, M. Azad
Tahir, M. Nawaz
Chohan, Zahid H.
Thebo, Khalid H.
Helliwell, Madeleine
author_sort Shad, Hazoor A.
collection PubMed
description The title compound, [Bi(C(8)H(18)PS(2))(3)], contains a Bi(III) cation surrounded by three bis­(2-methyl­prop­yl)dithio­phosphinate anions, leading to a distorted octa­hedral coordination for the heavy metal. The Bi—S and S—P bond lengths are in the ranges 2.7694 (18)–2.8391 (17) and 2.019 (2)–2.035 (2) Å, respectively. The crystal structure is consolidated by C—H⋯S hydrogen bonds. Intra­molecular C—H⋯π inter­actions also play a role in stabilizing the mol­ecules.
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spelling pubmed-29796052010-12-30 Tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(III) Shad, Hazoor A. Malik, M. Azad Tahir, M. Nawaz Chohan, Zahid H. Thebo, Khalid H. Helliwell, Madeleine Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Bi(C(8)H(18)PS(2))(3)], contains a Bi(III) cation surrounded by three bis­(2-methyl­prop­yl)dithio­phosphinate anions, leading to a distorted octa­hedral coordination for the heavy metal. The Bi—S and S—P bond lengths are in the ranges 2.7694 (18)–2.8391 (17) and 2.019 (2)–2.035 (2) Å, respectively. The crystal structure is consolidated by C—H⋯S hydrogen bonds. Intra­molecular C—H⋯π inter­actions also play a role in stabilizing the mol­ecules. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979605/ /pubmed/21579267 http://dx.doi.org/10.1107/S1600536810015618 Text en © Shad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shad, Hazoor A.
Malik, M. Azad
Tahir, M. Nawaz
Chohan, Zahid H.
Thebo, Khalid H.
Helliwell, Madeleine
Tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(III)
title Tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(III)
title_full Tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(III)
title_fullStr Tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(III)
title_full_unstemmed Tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(III)
title_short Tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(III)
title_sort tris[bis­(2-methyl­prop­yl)dithio­phosphinato]bis­muth(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979605/
https://www.ncbi.nlm.nih.gov/pubmed/21579267
http://dx.doi.org/10.1107/S1600536810015618
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