(+)-{1,2-Bis[(2R,5R)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) P,P′}(η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluorido­borate

The title compound, [Rh(C(8)H(12))(C(14)H(28)P(2))]BF(4), exhibits a rhodium(I) complex cation with a bidentate bis­phosphine ligand and a bidentate η(2),η(2)-coordinated cyclo­octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom....

Descripción completa

Detalles Bibliográficos
Autores principales: Schulz, Stefan, Drexler, Hans-Joachim, Heller, Detlef
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979608/
https://www.ncbi.nlm.nih.gov/pubmed/21579351
http://dx.doi.org/10.1107/S1600536810019859
Descripción
Sumario:The title compound, [Rh(C(8)H(12))(C(14)H(28)P(2))]BF(4), exhibits a rhodium(I) complex cation with a bidentate bis­phosphine ligand and a bidentate η(2),η(2)-coordinated cyclo­octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three mol­ecules in the asymmetric unit and intra­molecular P—Rh—P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P—Rh—P and the X—Rh—X planes (X is the centroid of a double bond) are 14.7 (1), 14.8 (1) and 15.3 (1)°. The structure exhibits disorder of one cyclo­octa­diene ligand as well as one BF(4) anion.

Ejemplares similares