(+)-{1,2-Bis[(2R,5R)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) P,P′}(η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluorido­borate

The title compound, [Rh(C(8)H(12))(C(14)H(28)P(2))]BF(4), exhibits a rhodium(I) complex cation with a bidentate bis­phosphine ligand and a bidentate η(2),η(2)-coordinated cyclo­octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom....

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Detalles Bibliográficos
Autores principales: Schulz, Stefan, Drexler, Hans-Joachim, Heller, Detlef
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979608/
https://www.ncbi.nlm.nih.gov/pubmed/21579351
http://dx.doi.org/10.1107/S1600536810019859
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author Schulz, Stefan
Drexler, Hans-Joachim
Heller, Detlef
author_facet Schulz, Stefan
Drexler, Hans-Joachim
Heller, Detlef
author_sort Schulz, Stefan
collection PubMed
description The title compound, [Rh(C(8)H(12))(C(14)H(28)P(2))]BF(4), exhibits a rhodium(I) complex cation with a bidentate bis­phosphine ligand and a bidentate η(2),η(2)-coordinated cyclo­octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three mol­ecules in the asymmetric unit and intra­molecular P—Rh—P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P—Rh—P and the X—Rh—X planes (X is the centroid of a double bond) are 14.7 (1), 14.8 (1) and 15.3 (1)°. The structure exhibits disorder of one cyclo­octa­diene ligand as well as one BF(4) anion.
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spelling pubmed-29796082010-12-30 (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) P,P′}(η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluorido­borate Schulz, Stefan Drexler, Hans-Joachim Heller, Detlef Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Rh(C(8)H(12))(C(14)H(28)P(2))]BF(4), exhibits a rhodium(I) complex cation with a bidentate bis­phosphine ligand and a bidentate η(2),η(2)-coordinated cyclo­octa-1,5-diene. Together the ligands create a slightly distorted square-planar cordination environment for the Rh(I) atom. There are three mol­ecules in the asymmetric unit and intra­molecular P—Rh—P bite angles of 82.78 (5), 82.97 (6) and 83.09 (5)° are observed. The dihedral angles between the P—Rh—P and the X—Rh—X planes (X is the centroid of a double bond) are 14.7 (1), 14.8 (1) and 15.3 (1)°. The structure exhibits disorder of one cyclo­octa­diene ligand as well as one BF(4) anion. International Union of Crystallography 2010-05-29 /pmc/articles/PMC2979608/ /pubmed/21579351 http://dx.doi.org/10.1107/S1600536810019859 Text en © Schulz et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Schulz, Stefan
Drexler, Hans-Joachim
Heller, Detlef
(+)-{1,2-Bis[(2R,5R)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) P,P′}(η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluorido­borate
title (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) P,P′}(η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluorido­borate
title_full (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) P,P′}(η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluorido­borate
title_fullStr (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) P,P′}(η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluorido­borate
title_full_unstemmed (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) P,P′}(η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluorido­borate
title_short (+)-{1,2-Bis[(2R,5R)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) P,P′}(η(4)-cyclo­octa-1,5-diene)rhodium(I) tetra­fluorido­borate
title_sort (+)-{1,2-bis[(2r,5r)-2,5-dimethyl­phospho­lan-1-yl]ethane-κ(2) p,p′}(η(4)-cyclo­octa-1,5-diene)rhodium(i) tetra­fluorido­borate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979608/
https://www.ncbi.nlm.nih.gov/pubmed/21579351
http://dx.doi.org/10.1107/S1600536810019859
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AT hellerdetlef 12bis2r5r25dimethylphospholan1ylethanek2ppē4cycloocta15dienerhodiumitetrafluoridoborate

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