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Tris{N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido}(triphenylphosphine oxide)holmium(III)
In the title compound, [Ho(C(6)H(12)Cl(3)N(3)O(2)P)(3)(C(18)H(15)OP)], the Ho(III) ion is surrounded by six O atoms from the three bidentate N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido ligands (L (−)) and by one O atom from the triphenylphosphine oxide ligand, with the formation...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979613/ https://www.ncbi.nlm.nih.gov/pubmed/21579292 http://dx.doi.org/10.1107/S160053681001665X |
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author | Amirkhanov, Oleksiy V. Marchenko, Ivan O. Moroz, Olesia V. Sliva, Tetyana Yu. Fritsky, Igor O. |
author_facet | Amirkhanov, Oleksiy V. Marchenko, Ivan O. Moroz, Olesia V. Sliva, Tetyana Yu. Fritsky, Igor O. |
author_sort | Amirkhanov, Oleksiy V. |
collection | PubMed |
description | In the title compound, [Ho(C(6)H(12)Cl(3)N(3)O(2)P)(3)(C(18)H(15)OP)], the Ho(III) ion is surrounded by six O atoms from the three bidentate N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido ligands (L (−)) and by one O atom from the triphenylphosphine oxide ligand, with the formation of a distorted monocapped octahedron. In one ligand L (−), the trichloromethyl group is rotationally disordered between two orientations in a 1:1 ratio, while two dimethylamino groups in another ligand L (−) are disordered between two conformations, each with the same 1:1 ratio. |
format | Text |
id | pubmed-2979613 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29796132010-12-30 Tris{N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido}(triphenylphosphine oxide)holmium(III) Amirkhanov, Oleksiy V. Marchenko, Ivan O. Moroz, Olesia V. Sliva, Tetyana Yu. Fritsky, Igor O. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ho(C(6)H(12)Cl(3)N(3)O(2)P)(3)(C(18)H(15)OP)], the Ho(III) ion is surrounded by six O atoms from the three bidentate N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido ligands (L (−)) and by one O atom from the triphenylphosphine oxide ligand, with the formation of a distorted monocapped octahedron. In one ligand L (−), the trichloromethyl group is rotationally disordered between two orientations in a 1:1 ratio, while two dimethylamino groups in another ligand L (−) are disordered between two conformations, each with the same 1:1 ratio. International Union of Crystallography 2010-05-12 /pmc/articles/PMC2979613/ /pubmed/21579292 http://dx.doi.org/10.1107/S160053681001665X Text en © Amirkhanov et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Amirkhanov, Oleksiy V. Marchenko, Ivan O. Moroz, Olesia V. Sliva, Tetyana Yu. Fritsky, Igor O. Tris{N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido}(triphenylphosphine oxide)holmium(III) |
title | Tris{N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido}(triphenylphosphine oxide)holmium(III) |
title_full | Tris{N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido}(triphenylphosphine oxide)holmium(III) |
title_fullStr | Tris{N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido}(triphenylphosphine oxide)holmium(III) |
title_full_unstemmed | Tris{N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido}(triphenylphosphine oxide)holmium(III) |
title_short | Tris{N-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido}(triphenylphosphine oxide)holmium(III) |
title_sort | tris{n-[bis(dimethylamino)phosphinoyl]-2,2,2-trichloroacetamido}(triphenylphosphine oxide)holmium(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979613/ https://www.ncbi.nlm.nih.gov/pubmed/21579292 http://dx.doi.org/10.1107/S160053681001665X |
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