Cargando…

Tris{N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido}(triphenyl­phosphine oxide)holmium(III)

In the title compound, [Ho(C(6)H(12)Cl(3)N(3)O(2)P)(3)(C(18)H(15)OP)], the Ho(III) ion is surrounded by six O atoms from the three bidentate N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido ligands (L (−)) and by one O atom from the triphenyl­phosphine oxide ligand, with the formation...

Descripción completa

Detalles Bibliográficos
Autores principales: Amirkhanov, Oleksiy V., Marchenko, Ivan O., Moroz, Olesia V., Sliva, Tetyana Yu., Fritsky, Igor O.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979613/
https://www.ncbi.nlm.nih.gov/pubmed/21579292
http://dx.doi.org/10.1107/S160053681001665X
_version_ 1782191455125635072
author Amirkhanov, Oleksiy V.
Marchenko, Ivan O.
Moroz, Olesia V.
Sliva, Tetyana Yu.
Fritsky, Igor O.
author_facet Amirkhanov, Oleksiy V.
Marchenko, Ivan O.
Moroz, Olesia V.
Sliva, Tetyana Yu.
Fritsky, Igor O.
author_sort Amirkhanov, Oleksiy V.
collection PubMed
description In the title compound, [Ho(C(6)H(12)Cl(3)N(3)O(2)P)(3)(C(18)H(15)OP)], the Ho(III) ion is surrounded by six O atoms from the three bidentate N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido ligands (L (−)) and by one O atom from the triphenyl­phosphine oxide ligand, with the formation of a distorted monocapped octa­hedron. In one ligand L (−), the trichloro­methyl group is rotationally disordered between two orientations in a 1:1 ratio, while two dimethyl­amino groups in another ligand L (−) are disordered between two conformations, each with the same 1:1 ratio.
format Text
id pubmed-2979613
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29796132010-12-30 Tris{N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido}(triphenyl­phosphine oxide)holmium(III) Amirkhanov, Oleksiy V. Marchenko, Ivan O. Moroz, Olesia V. Sliva, Tetyana Yu. Fritsky, Igor O. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ho(C(6)H(12)Cl(3)N(3)O(2)P)(3)(C(18)H(15)OP)], the Ho(III) ion is surrounded by six O atoms from the three bidentate N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido ligands (L (−)) and by one O atom from the triphenyl­phosphine oxide ligand, with the formation of a distorted monocapped octa­hedron. In one ligand L (−), the trichloro­methyl group is rotationally disordered between two orientations in a 1:1 ratio, while two dimethyl­amino groups in another ligand L (−) are disordered between two conformations, each with the same 1:1 ratio. International Union of Crystallography 2010-05-12 /pmc/articles/PMC2979613/ /pubmed/21579292 http://dx.doi.org/10.1107/S160053681001665X Text en © Amirkhanov et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Amirkhanov, Oleksiy V.
Marchenko, Ivan O.
Moroz, Olesia V.
Sliva, Tetyana Yu.
Fritsky, Igor O.
Tris{N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido}(triphenyl­phosphine oxide)holmium(III)
title Tris{N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido}(triphenyl­phosphine oxide)holmium(III)
title_full Tris{N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido}(triphenyl­phosphine oxide)holmium(III)
title_fullStr Tris{N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido}(triphenyl­phosphine oxide)holmium(III)
title_full_unstemmed Tris{N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido}(triphenyl­phosphine oxide)holmium(III)
title_short Tris{N-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido}(triphenyl­phosphine oxide)holmium(III)
title_sort tris{n-[bis­(dimethyl­amino)phosphino­yl]-2,2,2-trichloro­acetamido}(triphenyl­phosphine oxide)holmium(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979613/
https://www.ncbi.nlm.nih.gov/pubmed/21579292
http://dx.doi.org/10.1107/S160053681001665X
work_keys_str_mv AT amirkhanovoleksiyv trisnbisdimethylaminophosphinoyl222trichloroacetamidotriphenylphosphineoxideholmiumiii
AT marchenkoivano trisnbisdimethylaminophosphinoyl222trichloroacetamidotriphenylphosphineoxideholmiumiii
AT morozolesiav trisnbisdimethylaminophosphinoyl222trichloroacetamidotriphenylphosphineoxideholmiumiii
AT slivatetyanayu trisnbisdimethylaminophosphinoyl222trichloroacetamidotriphenylphosphineoxideholmiumiii
AT fritskyigoro trisnbisdimethylaminophosphinoyl222trichloroacetamidotriphenylphosphineoxideholmiumiii