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Bis(μ-4-fluoro-2,6-diformylphenolato)bis[diaquanickel(II)] dichloride
In the title dinuclear nickel(II) complex, [Ni(2)(C(8)H(4)FO(3))(2)(H(2)O)(4)]Cl(2), synthesized by the reaction between 4-fluoro-2,6-diformylphenol and nickel(II) chloride in methanol, the coordination cation is located on an inversion center and the Ni(II) atom adopts a slightly distorted octahe...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979620/ https://www.ncbi.nlm.nih.gov/pubmed/21579311 http://dx.doi.org/10.1107/S1600536810016284 |
| Sumario: | In the title dinuclear nickel(II) complex, [Ni(2)(C(8)H(4)FO(3))(2)(H(2)O)(4)]Cl(2), synthesized by the reaction between 4-fluoro-2,6-diformylphenol and nickel(II) chloride in methanol, the coordination cation is located on an inversion center and the Ni(II) atom adopts a slightly distorted octahedral coordination geometry. The two Ni atoms are bridged by two phenolate O atoms and the intramolecular Ni⋯Ni distance is 3.0751 (9) Å. The crystal structure is stabilized by O—H⋯Cl hydrogen bonds. |
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