Bis(μ-4-fluoro-2,6-diformyl­phenolato)bis­[diaqua­nickel(II)] dichloride

In the title dinuclear nickel(II) complex, [Ni(2)(C(8)H(4)FO(3))(2)(H(2)O)(4)]Cl(2), synthesized by the reaction between 4-fluoro-2,6-diformyl­phenol and nickel(II) chloride in methanol, the coordination cation is located on an inversion center and the Ni(II) atom adopts a slightly distorted octa­he...

Descripción completa

Detalles Bibliográficos
Autores principales: Zheng, Yin, Li, Shi-Rong, Zhou, Hong, Pan, Zhi-Quan, Li, Yi-Zhi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979620/
https://www.ncbi.nlm.nih.gov/pubmed/21579311
http://dx.doi.org/10.1107/S1600536810016284
_version_ 1782191456747782144
author Zheng, Yin
Li, Shi-Rong
Zhou, Hong
Pan, Zhi-Quan
Li, Yi-Zhi
author_facet Zheng, Yin
Li, Shi-Rong
Zhou, Hong
Pan, Zhi-Quan
Li, Yi-Zhi
author_sort Zheng, Yin
collection PubMed
description In the title dinuclear nickel(II) complex, [Ni(2)(C(8)H(4)FO(3))(2)(H(2)O)(4)]Cl(2), synthesized by the reaction between 4-fluoro-2,6-diformyl­phenol and nickel(II) chloride in methanol, the coordination cation is located on an inversion center and the Ni(II) atom adopts a slightly distorted octa­hedral coordination geometry. The two Ni atoms are bridged by two phenolate O atoms and the intra­molecular Ni⋯Ni distance is 3.0751 (9) Å. The crystal structure is stabilized by O—H⋯Cl hydrogen bonds.
format Text
id pubmed-2979620
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29796202010-12-30 Bis(μ-4-fluoro-2,6-diformyl­phenolato)bis­[diaqua­nickel(II)] dichloride Zheng, Yin Li, Shi-Rong Zhou, Hong Pan, Zhi-Quan Li, Yi-Zhi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title dinuclear nickel(II) complex, [Ni(2)(C(8)H(4)FO(3))(2)(H(2)O)(4)]Cl(2), synthesized by the reaction between 4-fluoro-2,6-diformyl­phenol and nickel(II) chloride in methanol, the coordination cation is located on an inversion center and the Ni(II) atom adopts a slightly distorted octa­hedral coordination geometry. The two Ni atoms are bridged by two phenolate O atoms and the intra­molecular Ni⋯Ni distance is 3.0751 (9) Å. The crystal structure is stabilized by O—H⋯Cl hydrogen bonds. International Union of Crystallography 2010-05-19 /pmc/articles/PMC2979620/ /pubmed/21579311 http://dx.doi.org/10.1107/S1600536810016284 Text en © Zheng et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zheng, Yin
Li, Shi-Rong
Zhou, Hong
Pan, Zhi-Quan
Li, Yi-Zhi
Bis(μ-4-fluoro-2,6-diformyl­phenolato)bis­[diaqua­nickel(II)] dichloride
title Bis(μ-4-fluoro-2,6-diformyl­phenolato)bis­[diaqua­nickel(II)] dichloride
title_full Bis(μ-4-fluoro-2,6-diformyl­phenolato)bis­[diaqua­nickel(II)] dichloride
title_fullStr Bis(μ-4-fluoro-2,6-diformyl­phenolato)bis­[diaqua­nickel(II)] dichloride
title_full_unstemmed Bis(μ-4-fluoro-2,6-diformyl­phenolato)bis­[diaqua­nickel(II)] dichloride
title_short Bis(μ-4-fluoro-2,6-diformyl­phenolato)bis­[diaqua­nickel(II)] dichloride
title_sort bis(μ-4-fluoro-2,6-diformyl­phenolato)bis­[diaqua­nickel(ii)] dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979620/
https://www.ncbi.nlm.nih.gov/pubmed/21579311
http://dx.doi.org/10.1107/S1600536810016284
work_keys_str_mv AT zhengyin bism4fluoro26diformylphenolatobisdiaquanickeliidichloride
AT lishirong bism4fluoro26diformylphenolatobisdiaquanickeliidichloride
AT zhouhong bism4fluoro26diformylphenolatobisdiaquanickeliidichloride
AT panzhiquan bism4fluoro26diformylphenolatobisdiaquanickeliidichloride
AT liyizhi bism4fluoro26diformylphenolatobisdiaquanickeliidichloride

Ejemplares similares