2-Iodo-5-nitro­thio­phene

The title compound, C(4)H(2)INO(2)S, was synthesized by nitration of iodo­thio­phene with acetyl nitrate. The molecule is essentially planar, withthe nitro group tilted by 1.78 (19)° and the iodine atom displaced by 0.0233 (2) Å with respect to the thiophene ring. In the crystal structure, adjacent...

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Detalles Bibliográficos
Autores principales: Xu, Xing Yan, Huang, Gang, Zeng, Xiang Chao, Hu, Fang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979622/
https://www.ncbi.nlm.nih.gov/pubmed/21579486
http://dx.doi.org/10.1107/S1600536810017356
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author Xu, Xing Yan
Huang, Gang
Zeng, Xiang Chao
Hu, Fang
author_facet Xu, Xing Yan
Huang, Gang
Zeng, Xiang Chao
Hu, Fang
author_sort Xu, Xing Yan
collection PubMed
description The title compound, C(4)H(2)INO(2)S, was synthesized by nitration of iodo­thio­phene with acetyl nitrate. The molecule is essentially planar, withthe nitro group tilted by 1.78 (19)° and the iodine atom displaced by 0.0233 (2) Å with respect to the thiophene ring. In the crystal structure, adjacent mol­ecules are linked through weak I⋯O inter­actions [3.039 (2)Å], forming chains extending along the b axis.
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spelling pubmed-29796222010-12-30 2-Iodo-5-nitro­thio­phene Xu, Xing Yan Huang, Gang Zeng, Xiang Chao Hu, Fang Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(4)H(2)INO(2)S, was synthesized by nitration of iodo­thio­phene with acetyl nitrate. The molecule is essentially planar, withthe nitro group tilted by 1.78 (19)° and the iodine atom displaced by 0.0233 (2) Å with respect to the thiophene ring. In the crystal structure, adjacent mol­ecules are linked through weak I⋯O inter­actions [3.039 (2)Å], forming chains extending along the b axis. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979622/ /pubmed/21579486 http://dx.doi.org/10.1107/S1600536810017356 Text en © Xu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Xu, Xing Yan
Huang, Gang
Zeng, Xiang Chao
Hu, Fang
2-Iodo-5-nitro­thio­phene
title 2-Iodo-5-nitro­thio­phene
title_full 2-Iodo-5-nitro­thio­phene
title_fullStr 2-Iodo-5-nitro­thio­phene
title_full_unstemmed 2-Iodo-5-nitro­thio­phene
title_short 2-Iodo-5-nitro­thio­phene
title_sort 2-iodo-5-nitro­thio­phene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979622/
https://www.ncbi.nlm.nih.gov/pubmed/21579486
http://dx.doi.org/10.1107/S1600536810017356
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AT huanggang 2iodo5nitrothiophene
AT zengxiangchao 2iodo5nitrothiophene
AT hufang 2iodo5nitrothiophene

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