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{3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}nickel(II)
The title square-planar nickel complex, [Ni(C(20)H(22)N(2)O(6))], has Ni—N and Ni—O bond lengths of 1.8448 (14)/1.8478 (14) and 1.8536 (12)/1.8520 (12) Å. There is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 11.11 (5)°]. All the atoms of the methoxy substitu...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979626/ https://www.ncbi.nlm.nih.gov/pubmed/21579278 http://dx.doi.org/10.1107/S1600536810016041 |
| Sumario: | The title square-planar nickel complex, [Ni(C(20)H(22)N(2)O(6))], has Ni—N and Ni—O bond lengths of 1.8448 (14)/1.8478 (14) and 1.8536 (12)/1.8520 (12) Å. There is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 11.11 (5)°]. All the atoms of the methoxy substitutents are in the plane of the ring to which they are attached except for one which deviates slightly [0.365 (3) Å]. In the crystal, weak C—H⋯O intermolecular interactions connect the molecules. |
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