{3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)

The title square-planar nickel complex, [Ni(C(20)H(22)N(2)O(6))], has Ni—N and Ni—O bond lengths of 1.8448 (14)/1.8478 (14) and 1.8536 (12)/1.8520 (12) Å. There is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 11.11 (5)°]. All the atoms of the meth­oxy substitu...

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Detalles Bibliográficos
Autores principales: Assey, Gervas E., Butcher, Ray J., Gultneh, Yilma
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979626/
https://www.ncbi.nlm.nih.gov/pubmed/21579278
http://dx.doi.org/10.1107/S1600536810016041
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author Assey, Gervas E.
Butcher, Ray J.
Gultneh, Yilma
author_facet Assey, Gervas E.
Butcher, Ray J.
Gultneh, Yilma
author_sort Assey, Gervas E.
collection PubMed
description The title square-planar nickel complex, [Ni(C(20)H(22)N(2)O(6))], has Ni—N and Ni—O bond lengths of 1.8448 (14)/1.8478 (14) and 1.8536 (12)/1.8520 (12) Å. There is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 11.11 (5)°]. All the atoms of the meth­oxy substitutents are in the plane of the ring to which they are attached except for one which deviates slightly [0.365 (3) Å]. In the crystal, weak C—H⋯O inter­molecular inter­actions connect the mol­ecules.
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spelling pubmed-29796262010-12-30 {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II) Assey, Gervas E. Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title square-planar nickel complex, [Ni(C(20)H(22)N(2)O(6))], has Ni—N and Ni—O bond lengths of 1.8448 (14)/1.8478 (14) and 1.8536 (12)/1.8520 (12) Å. There is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 11.11 (5)°]. All the atoms of the meth­oxy substitutents are in the plane of the ring to which they are attached except for one which deviates slightly [0.365 (3) Å]. In the crystal, weak C—H⋯O inter­molecular inter­actions connect the mol­ecules. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979626/ /pubmed/21579278 http://dx.doi.org/10.1107/S1600536810016041 Text en © Assey et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Assey, Gervas E.
Butcher, Ray J.
Gultneh, Yilma
{3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_full {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_fullStr {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_full_unstemmed {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_short {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)
title_sort {3,3′,5,5′-tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979626/
https://www.ncbi.nlm.nih.gov/pubmed/21579278
http://dx.doi.org/10.1107/S1600536810016041
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AT butcherrayj 3355tetramethoxy22ethane12diylbisnitrilomethylidynediphenolatonickelii
AT gultnehyilma 3355tetramethoxy22ethane12diylbisnitrilomethylidynediphenolatonickelii

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