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9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π interactions between the acridine ring systems. These dimers are further linked by C—H⋯π and C—Br⋯π interactions. The cations and anions are connected by multidirecti...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979630/ https://www.ncbi.nlm.nih.gov/pubmed/21579407 http://dx.doi.org/10.1107/S1600536810016296 |
Sumario: | In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π interactions between the acridine ring systems. These dimers are further linked by C—H⋯π and C—Br⋯π interactions. The cations and anions are connected by multidirectional C—H⋯O and C—F⋯π interactions. The acridine and benzene ring systems are oriented at 10.8 (1)°. The carboxyl group is twisted at an angle of 85.2 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel or almost parallel [inclined at an angle of 1.4 (1)°] in the crystal structure. |
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