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9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate
In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π interactions between the acridine ring systems. These dimers are further linked by C—H⋯π and C—Br⋯π interactions. The cations and anions are connected by multidirecti...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979630/ https://www.ncbi.nlm.nih.gov/pubmed/21579407 http://dx.doi.org/10.1107/S1600536810016296 |
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author | Trzybiński, Damian Krzymiński, Karol Sikorski, Artur Błażejowski, Jerzy |
author_facet | Trzybiński, Damian Krzymiński, Karol Sikorski, Artur Błażejowski, Jerzy |
author_sort | Trzybiński, Damian |
collection | PubMed |
description | In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π interactions between the acridine ring systems. These dimers are further linked by C—H⋯π and C—Br⋯π interactions. The cations and anions are connected by multidirectional C—H⋯O and C—F⋯π interactions. The acridine and benzene ring systems are oriented at 10.8 (1)°. The carboxyl group is twisted at an angle of 85.2 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel or almost parallel [inclined at an angle of 1.4 (1)°] in the crystal structure. |
format | Text |
id | pubmed-2979630 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29796302010-12-30 9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate Trzybiński, Damian Krzymiński, Karol Sikorski, Artur Błażejowski, Jerzy Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal structure of the title compound, C(21)H(15)BrNO(2) (+)·CF(3)SO(3) (−), the cations form inversion dimers through π–π interactions between the acridine ring systems. These dimers are further linked by C—H⋯π and C—Br⋯π interactions. The cations and anions are connected by multidirectional C—H⋯O and C—F⋯π interactions. The acridine and benzene ring systems are oriented at 10.8 (1)°. The carboxyl group is twisted at an angle of 85.2 (1)° relative to the acridine skeleton. The mean planes of adjacent acridine units are parallel or almost parallel [inclined at an angle of 1.4 (1)°] in the crystal structure. International Union of Crystallography 2010-05-12 /pmc/articles/PMC2979630/ /pubmed/21579407 http://dx.doi.org/10.1107/S1600536810016296 Text en © Trzybiński et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Trzybiński, Damian Krzymiński, Karol Sikorski, Artur Błażejowski, Jerzy 9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title | 9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_full | 9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_fullStr | 9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_full_unstemmed | 9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_short | 9-(4-Bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
title_sort | 9-(4-bromophenoxycarbonyl)-10-methylacridinium trifluoromethanesulfonate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979630/ https://www.ncbi.nlm.nih.gov/pubmed/21579407 http://dx.doi.org/10.1107/S1600536810016296 |
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