Hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(V) monohydrate

In the title compound, (C(2)H(8)N)(6)[V(10)O(28)]·H(2)O, the [V(10)O(28)](6−) polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the V(V) atoms adopts a distorted octa­hedral geometry. Eight terminal O atoms are bonded to V(V) a...

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Detalles Bibliográficos
Autores principales: Wang, Sulian, Lu, Liping, Feng, Sisi, Zhu, Miaoli
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979636/
https://www.ncbi.nlm.nih.gov/pubmed/21579286
http://dx.doi.org/10.1107/S1600536810016442
Descripción
Sumario:In the title compound, (C(2)H(8)N)(6)[V(10)O(28)]·H(2)O, the [V(10)O(28)](6−) polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the V(V) atoms adopts a distorted octa­hedral geometry. Eight terminal O atoms are bonded to V(V) atoms with double bonds and the others act as bridging atoms. In the crystal structure, a network of N—H⋯O and O—H⋯O hydrogen bonds helps to establish the packing.

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