Hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(V) monohydrate

In the title compound, (C(2)H(8)N)(6)[V(10)O(28)]·H(2)O, the [V(10)O(28)](6−) polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the V(V) atoms adopts a distorted octa­hedral geometry. Eight terminal O atoms are bonded to V(V) a...

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Detalles Bibliográficos
Autores principales: Wang, Sulian, Lu, Liping, Feng, Sisi, Zhu, Miaoli
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979636/
https://www.ncbi.nlm.nih.gov/pubmed/21579286
http://dx.doi.org/10.1107/S1600536810016442
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author Wang, Sulian
Lu, Liping
Feng, Sisi
Zhu, Miaoli
author_facet Wang, Sulian
Lu, Liping
Feng, Sisi
Zhu, Miaoli
author_sort Wang, Sulian
collection PubMed
description In the title compound, (C(2)H(8)N)(6)[V(10)O(28)]·H(2)O, the [V(10)O(28)](6−) polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the V(V) atoms adopts a distorted octa­hedral geometry. Eight terminal O atoms are bonded to V(V) atoms with double bonds and the others act as bridging atoms. In the crystal structure, a network of N—H⋯O and O—H⋯O hydrogen bonds helps to establish the packing.
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spelling pubmed-29796362010-12-30 Hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(V) monohydrate Wang, Sulian Lu, Liping Feng, Sisi Zhu, Miaoli Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, (C(2)H(8)N)(6)[V(10)O(28)]·H(2)O, the [V(10)O(28)](6−) polymetalate anion has crystallographic mirror symmetry with six V atoms and 12 O atoms lying on the mirror plane. Each of the V(V) atoms adopts a distorted octa­hedral geometry. Eight terminal O atoms are bonded to V(V) atoms with double bonds and the others act as bridging atoms. In the crystal structure, a network of N—H⋯O and O—H⋯O hydrogen bonds helps to establish the packing. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979636/ /pubmed/21579286 http://dx.doi.org/10.1107/S1600536810016442 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Sulian
Lu, Liping
Feng, Sisi
Zhu, Miaoli
Hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(V) monohydrate
title Hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(V) monohydrate
title_full Hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(V) monohydrate
title_fullStr Hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(V) monohydrate
title_full_unstemmed Hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(V) monohydrate
title_short Hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(V) monohydrate
title_sort hexakis(dimethyl­ammonium) di-μ(6)-oxido-tetra-μ(3)-oxido-tetra­deca-μ(2)-oxido-octa­oxidodeca­vanadate(v) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979636/
https://www.ncbi.nlm.nih.gov/pubmed/21579286
http://dx.doi.org/10.1107/S1600536810016442
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AT fengsisi hexakisdimethylammoniumdim6oxidotetram3oxidotetradecam2oxidooctaoxidodecavanadatevmonohydrate
AT zhumiaoli hexakisdimethylammoniumdim6oxidotetram3oxidotetradecam2oxidooctaoxidodecavanadatevmonohydrate

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