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{3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenol­ato}­copper(II)

In the title square-planar copper complex, [Cu(C(20)H(22)N(2)O(6))], the Cu—N and Cu—O bond lengths are significantly longer than those of its isostructural nickel analog. The title structure is related to that of the corresponding monohydrate. There are significant differences in the conformations...

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Detalles Bibliográficos
Autores principales: Assey, Gervas, Butcher, Ray J., Gultneh, Yilma
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979637/
https://www.ncbi.nlm.nih.gov/pubmed/21579299
http://dx.doi.org/10.1107/S1600536810017137
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author Assey, Gervas
Butcher, Ray J.
Gultneh, Yilma
author_facet Assey, Gervas
Butcher, Ray J.
Gultneh, Yilma
author_sort Assey, Gervas
collection PubMed
description In the title square-planar copper complex, [Cu(C(20)H(22)N(2)O(6))], the Cu—N and Cu—O bond lengths are significantly longer than those of its isostructural nickel analog. The title structure is related to that of the corresponding monohydrate. There are significant differences in the conformations of the two complexes. While the monohydrate is mainly planar, in the title compound there is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 13.14 (6)°]. All the atoms of the meth­oxy substitutents are in the plane of the ring to which they are attached (r.m.s. deviation = 0.0079 Å) except for one of the meth­oxy C atoms, which deviates slightly [0.309 (4) Å]. In the crystal, weak C—H⋯O inter­molecular inter­actions link the mol­ecules.
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spelling pubmed-29796372010-12-30 {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenol­ato}­copper(II) Assey, Gervas Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title square-planar copper complex, [Cu(C(20)H(22)N(2)O(6))], the Cu—N and Cu—O bond lengths are significantly longer than those of its isostructural nickel analog. The title structure is related to that of the corresponding monohydrate. There are significant differences in the conformations of the two complexes. While the monohydrate is mainly planar, in the title compound there is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 13.14 (6)°]. All the atoms of the meth­oxy substitutents are in the plane of the ring to which they are attached (r.m.s. deviation = 0.0079 Å) except for one of the meth­oxy C atoms, which deviates slightly [0.309 (4) Å]. In the crystal, weak C—H⋯O inter­molecular inter­actions link the mol­ecules. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979637/ /pubmed/21579299 http://dx.doi.org/10.1107/S1600536810017137 Text en © Assey et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Assey, Gervas
Butcher, Ray J.
Gultneh, Yilma
{3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenol­ato}­copper(II)
title {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenol­ato}­copper(II)
title_full {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenol­ato}­copper(II)
title_fullStr {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenol­ato}­copper(II)
title_full_unstemmed {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenol­ato}­copper(II)
title_short {3,3′,5,5′-Tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenol­ato}­copper(II)
title_sort {3,3′,5,5′-tetra­meth­oxy-2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenol­ato}­copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979637/
https://www.ncbi.nlm.nih.gov/pubmed/21579299
http://dx.doi.org/10.1107/S1600536810017137
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