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{3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II)
In the title square-planar copper complex, [Cu(C(20)H(22)N(2)O(6))], the Cu—N and Cu—O bond lengths are significantly longer than those of its isostructural nickel analog. The title structure is related to that of the corresponding monohydrate. There are significant differences in the conformations...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979637/ https://www.ncbi.nlm.nih.gov/pubmed/21579299 http://dx.doi.org/10.1107/S1600536810017137 |
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author | Assey, Gervas Butcher, Ray J. Gultneh, Yilma |
author_facet | Assey, Gervas Butcher, Ray J. Gultneh, Yilma |
author_sort | Assey, Gervas |
collection | PubMed |
description | In the title square-planar copper complex, [Cu(C(20)H(22)N(2)O(6))], the Cu—N and Cu—O bond lengths are significantly longer than those of its isostructural nickel analog. The title structure is related to that of the corresponding monohydrate. There are significant differences in the conformations of the two complexes. While the monohydrate is mainly planar, in the title compound there is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 13.14 (6)°]. All the atoms of the methoxy substitutents are in the plane of the ring to which they are attached (r.m.s. deviation = 0.0079 Å) except for one of the methoxy C atoms, which deviates slightly [0.309 (4) Å]. In the crystal, weak C—H⋯O intermolecular interactions link the molecules. |
format | Text |
id | pubmed-2979637 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29796372010-12-30 {3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II) Assey, Gervas Butcher, Ray J. Gultneh, Yilma Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title square-planar copper complex, [Cu(C(20)H(22)N(2)O(6))], the Cu—N and Cu—O bond lengths are significantly longer than those of its isostructural nickel analog. The title structure is related to that of the corresponding monohydrate. There are significant differences in the conformations of the two complexes. While the monohydrate is mainly planar, in the title compound there is a slight twist in the two benzene rings at each end of the complex [dihedral angle = 13.14 (6)°]. All the atoms of the methoxy substitutents are in the plane of the ring to which they are attached (r.m.s. deviation = 0.0079 Å) except for one of the methoxy C atoms, which deviates slightly [0.309 (4) Å]. In the crystal, weak C—H⋯O intermolecular interactions link the molecules. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979637/ /pubmed/21579299 http://dx.doi.org/10.1107/S1600536810017137 Text en © Assey et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Assey, Gervas Butcher, Ray J. Gultneh, Yilma {3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title | {3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_full | {3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_fullStr | {3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_full_unstemmed | {3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_short | {3,3′,5,5′-Tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(II) |
title_sort | {3,3′,5,5′-tetramethoxy-2,2′-[ethane-1,2-diylbis(nitrilomethylidyne)]diphenolato}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979637/ https://www.ncbi.nlm.nih.gov/pubmed/21579299 http://dx.doi.org/10.1107/S1600536810017137 |
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