[(Z)-O-Ethyl N-(4-chloro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane hemisolvate

The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S—Au—P angle = 178.01 (4)°]; a close intra­molecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, mol­ecules are...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979641/
https://www.ncbi.nlm.nih.gov/pubmed/21579326
http://dx.doi.org/10.1107/S1600536810018179
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S—Au—P angle = 178.01 (4)°]; a close intra­molecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, mol­ecules are linked into supra­molecular chains propagating along [010] by C—H⋯N, C—H⋯S and C—H⋯π inter­actions. The solvent mol­ecule is disordered about a twofold rotation axis.
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spelling pubmed-29796412010-12-30 [(Z)-O-Ethyl N-(4-chloro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane hemisolvate Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S—Au—P angle = 178.01 (4)°]; a close intra­molecular Au⋯O contact [2.964 (4) Å] also occurs. In the crystal structure, mol­ecules are linked into supra­molecular chains propagating along [010] by C—H⋯N, C—H⋯S and C—H⋯π inter­actions. The solvent mol­ecule is disordered about a twofold rotation axis. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979641/ /pubmed/21579326 http://dx.doi.org/10.1107/S1600536810018179 Text en © Tadbuppa and Tiekink 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[(Z)-O-Ethyl N-(4-chloro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane hemisolvate
title [(Z)-O-Ethyl N-(4-chloro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane hemisolvate
title_full [(Z)-O-Ethyl N-(4-chloro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane hemisolvate
title_fullStr [(Z)-O-Ethyl N-(4-chloro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane hemisolvate
title_full_unstemmed [(Z)-O-Ethyl N-(4-chloro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane hemisolvate
title_short [(Z)-O-Ethyl N-(4-chloro­phen­yl)thio­carbamato-κS](triphenyl­phosphine-κP)gold(I) dichloro­methane hemisolvate
title_sort [(z)-o-ethyl n-(4-chloro­phen­yl)thio­carbamato-κs](triphenyl­phosphine-κp)gold(i) dichloro­methane hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979641/
https://www.ncbi.nlm.nih.gov/pubmed/21579326
http://dx.doi.org/10.1107/S1600536810018179
work_keys_str_mv AT tadbuppaprimjirap zoethyln4chlorophenylthiocarbamatokstriphenylphosphinekpgoldidichloromethanehemisolvate
AT tiekinkedwardrt zoethyln4chlorophenylthiocarbamatokstriphenylphosphinekpgoldidichloromethanehemisolvate

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