2-Amino-5-methyl­pyridinium picolinate 0.63-hydrate

The asymmetric unit of the title compound, C(6)H(9)N(2) (+)·C(6)H(4)NO(2) (−)·0.63H(2)O, contains two crystallographically independent 2-amino-5-methyl­pyridinium cations, a pair of picolinate anions and two water mol­ecules, one with an occupancy of 0.25. Both the 2-amino-5-methyl­pyridine mol­ecul...

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Detalles Bibliográficos
Autores principales: Hemamalini, Madhukar, Fun, Hoong-Kun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979649/
https://www.ncbi.nlm.nih.gov/pubmed/21579497
http://dx.doi.org/10.1107/S1600536810018180
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author Hemamalini, Madhukar
Fun, Hoong-Kun
author_facet Hemamalini, Madhukar
Fun, Hoong-Kun
author_sort Hemamalini, Madhukar
collection PubMed
description The asymmetric unit of the title compound, C(6)H(9)N(2) (+)·C(6)H(4)NO(2) (−)·0.63H(2)O, contains two crystallographically independent 2-amino-5-methyl­pyridinium cations, a pair of picolinate anions and two water mol­ecules, one with an occupancy of 0.25. Both the 2-amino-5-methyl­pyridine mol­ecules are protonated at the pyridine N atoms. In the crystal structure, the cations, anions and water mol­ecules are linked via N—H⋯O, N—H⋯N and O—H⋯O hydrogen bonds, as well as by C—H⋯O contacts, forming a chain along the b axis. In addition, weak π–π inter­actions are observed between pyridinium rings, with centroid–centroid distances of 3.5306 (13) Å.
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spelling pubmed-29796492010-12-30 2-Amino-5-methyl­pyridinium picolinate 0.63-hydrate Hemamalini, Madhukar Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(6)H(9)N(2) (+)·C(6)H(4)NO(2) (−)·0.63H(2)O, contains two crystallographically independent 2-amino-5-methyl­pyridinium cations, a pair of picolinate anions and two water mol­ecules, one with an occupancy of 0.25. Both the 2-amino-5-methyl­pyridine mol­ecules are protonated at the pyridine N atoms. In the crystal structure, the cations, anions and water mol­ecules are linked via N—H⋯O, N—H⋯N and O—H⋯O hydrogen bonds, as well as by C—H⋯O contacts, forming a chain along the b axis. In addition, weak π–π inter­actions are observed between pyridinium rings, with centroid–centroid distances of 3.5306 (13) Å. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979649/ /pubmed/21579497 http://dx.doi.org/10.1107/S1600536810018180 Text en © Hemamalini and Fun 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Hemamalini, Madhukar
Fun, Hoong-Kun
2-Amino-5-methyl­pyridinium picolinate 0.63-hydrate
title 2-Amino-5-methyl­pyridinium picolinate 0.63-hydrate
title_full 2-Amino-5-methyl­pyridinium picolinate 0.63-hydrate
title_fullStr 2-Amino-5-methyl­pyridinium picolinate 0.63-hydrate
title_full_unstemmed 2-Amino-5-methyl­pyridinium picolinate 0.63-hydrate
title_short 2-Amino-5-methyl­pyridinium picolinate 0.63-hydrate
title_sort 2-amino-5-methyl­pyridinium picolinate 0.63-hydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979649/
https://www.ncbi.nlm.nih.gov/pubmed/21579497
http://dx.doi.org/10.1107/S1600536810018180
work_keys_str_mv AT hemamalinimadhukar 2amino5methylpyridiniumpicolinate063hydrate
AT funhoongkun 2amino5methylpyridiniumpicolinate063hydrate

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