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Tris(ethyl­enediamine)cobalt(II) sulfate

The structure of the title compound, [Co(II)(C(2)H(8)N(2))(3)]SO(4), the cobalt example of [M(C(2)H(8)N(2))(3)]SO(4), is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethyl­enedi...

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Autores principales: Yotnoi, Bunlawee, Seeharaj, Athittaya, Chimupala, Yothin, Rujiwatra, Apinpus
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979650/
https://www.ncbi.nlm.nih.gov/pubmed/21579283
http://dx.doi.org/10.1107/S1600536810016168
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author Yotnoi, Bunlawee
Seeharaj, Athittaya
Chimupala, Yothin
Rujiwatra, Apinpus
author_facet Yotnoi, Bunlawee
Seeharaj, Athittaya
Chimupala, Yothin
Rujiwatra, Apinpus
author_sort Yotnoi, Bunlawee
collection PubMed
description The structure of the title compound, [Co(II)(C(2)H(8)N(2))(3)]SO(4), the cobalt example of [M(C(2)H(8)N(2))(3)]SO(4), is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethyl­enediamine mol­ecules generated from half of the ethyl­enediamine mol­ecule in the asymmetric unit. The O atoms of the sulfate anion are disordered mostly over two crystallographic sites. The third disorder site of O (site symmetry 3) has a site occupancy approaching zero. The H atoms of the ethyl­enediamine mol­ecules inter­act with the sulfate anions via inter­molecular N—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-29796502010-12-30 Tris(ethyl­enediamine)cobalt(II) sulfate Yotnoi, Bunlawee Seeharaj, Athittaya Chimupala, Yothin Rujiwatra, Apinpus Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Co(II)(C(2)H(8)N(2))(3)]SO(4), the cobalt example of [M(C(2)H(8)N(2))(3)]SO(4), is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethyl­enediamine mol­ecules generated from half of the ethyl­enediamine mol­ecule in the asymmetric unit. The O atoms of the sulfate anion are disordered mostly over two crystallographic sites. The third disorder site of O (site symmetry 3) has a site occupancy approaching zero. The H atoms of the ethyl­enediamine mol­ecules inter­act with the sulfate anions via inter­molecular N—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979650/ /pubmed/21579283 http://dx.doi.org/10.1107/S1600536810016168 Text en © Yotnoi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yotnoi, Bunlawee
Seeharaj, Athittaya
Chimupala, Yothin
Rujiwatra, Apinpus
Tris(ethyl­enediamine)cobalt(II) sulfate
title Tris(ethyl­enediamine)cobalt(II) sulfate
title_full Tris(ethyl­enediamine)cobalt(II) sulfate
title_fullStr Tris(ethyl­enediamine)cobalt(II) sulfate
title_full_unstemmed Tris(ethyl­enediamine)cobalt(II) sulfate
title_short Tris(ethyl­enediamine)cobalt(II) sulfate
title_sort tris(ethyl­enediamine)cobalt(ii) sulfate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979650/
https://www.ncbi.nlm.nih.gov/pubmed/21579283
http://dx.doi.org/10.1107/S1600536810016168
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AT chimupalayothin trisethylenediaminecobaltiisulfate
AT rujiwatraapinpus trisethylenediaminecobaltiisulfate