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Tris(ethylenediamine)cobalt(II) sulfate
The structure of the title compound, [Co(II)(C(2)H(8)N(2))(3)]SO(4), the cobalt example of [M(C(2)H(8)N(2))(3)]SO(4), is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethylenedi...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979650/ https://www.ncbi.nlm.nih.gov/pubmed/21579283 http://dx.doi.org/10.1107/S1600536810016168 |
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author | Yotnoi, Bunlawee Seeharaj, Athittaya Chimupala, Yothin Rujiwatra, Apinpus |
author_facet | Yotnoi, Bunlawee Seeharaj, Athittaya Chimupala, Yothin Rujiwatra, Apinpus |
author_sort | Yotnoi, Bunlawee |
collection | PubMed |
description | The structure of the title compound, [Co(II)(C(2)H(8)N(2))(3)]SO(4), the cobalt example of [M(C(2)H(8)N(2))(3)]SO(4), is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethylenediamine molecules generated from half of the ethylenediamine molecule in the asymmetric unit. The O atoms of the sulfate anion are disordered mostly over two crystallographic sites. The third disorder site of O (site symmetry 3) has a site occupancy approaching zero. The H atoms of the ethylenediamine molecules interact with the sulfate anions via intermolecular N—H⋯O hydrogen-bonding interactions. |
format | Text |
id | pubmed-2979650 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29796502010-12-30 Tris(ethylenediamine)cobalt(II) sulfate Yotnoi, Bunlawee Seeharaj, Athittaya Chimupala, Yothin Rujiwatra, Apinpus Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Co(II)(C(2)H(8)N(2))(3)]SO(4), the cobalt example of [M(C(2)H(8)N(2))(3)]SO(4), is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32), respectively. The Co atom is coordinated by six N atoms of three chelating ethylenediamine molecules generated from half of the ethylenediamine molecule in the asymmetric unit. The O atoms of the sulfate anion are disordered mostly over two crystallographic sites. The third disorder site of O (site symmetry 3) has a site occupancy approaching zero. The H atoms of the ethylenediamine molecules interact with the sulfate anions via intermolecular N—H⋯O hydrogen-bonding interactions. International Union of Crystallography 2010-05-08 /pmc/articles/PMC2979650/ /pubmed/21579283 http://dx.doi.org/10.1107/S1600536810016168 Text en © Yotnoi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yotnoi, Bunlawee Seeharaj, Athittaya Chimupala, Yothin Rujiwatra, Apinpus Tris(ethylenediamine)cobalt(II) sulfate |
title | Tris(ethylenediamine)cobalt(II) sulfate |
title_full | Tris(ethylenediamine)cobalt(II) sulfate |
title_fullStr | Tris(ethylenediamine)cobalt(II) sulfate |
title_full_unstemmed | Tris(ethylenediamine)cobalt(II) sulfate |
title_short | Tris(ethylenediamine)cobalt(II) sulfate |
title_sort | tris(ethylenediamine)cobalt(ii) sulfate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979650/ https://www.ncbi.nlm.nih.gov/pubmed/21579283 http://dx.doi.org/10.1107/S1600536810016168 |
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