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Poly[bis­(1H-imidazole)bis­(μ(2)-1H-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(II)]

The title polymer, [Zn(3)(C(8)H(8)O(5))(2)(C(3)H(3)N(2))(2)(C(3)H(4)N(2))(2)](n), was formed by the reaction of zinc acetate with imidazole and 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylic anhydride (norcan­tharidine). One of the two crystallographically unique Zn(II) atoms is four-coordinated by th...

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Detalles Bibliográficos
Autores principales: Lin, Qiu-Yue, Wang, Na, Wu, Yi-Zhou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979651/
https://www.ncbi.nlm.nih.gov/pubmed/21579339
http://dx.doi.org/10.1107/S1600536810017915
Descripción
Sumario:The title polymer, [Zn(3)(C(8)H(8)O(5))(2)(C(3)H(3)N(2))(2)(C(3)H(4)N(2))(2)](n), was formed by the reaction of zinc acetate with imidazole and 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylic anhydride (norcan­tharidine). One of the two crystallographically unique Zn(II) atoms is four-coordinated by three N atoms of three imidazole ligands, two of which are deprotonated, and by one carboxyl­ate O atom of the demethyl­cantharate anion. The second Zn(II) atom is situated on an inversion centre and is six-coordinated by the bridging O atoms of two symmetry-related demethyl­cantharate anions and by four carboxyl­ate O atoms of the corresponding carboxyl­ate groups. The polymeric crystal structure is additionally stabilized by N—H⋯O hydrogen bonding between the imidazole ligands and carboxyl­ate O atoms.