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Poly[bis­(1H-imidazole)bis­(μ(2)-1H-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(II)]

The title polymer, [Zn(3)(C(8)H(8)O(5))(2)(C(3)H(3)N(2))(2)(C(3)H(4)N(2))(2)](n), was formed by the reaction of zinc acetate with imidazole and 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylic anhydride (norcan­tharidine). One of the two crystallographically unique Zn(II) atoms is four-coordinated by th...

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Detalles Bibliográficos
Autores principales: Lin, Qiu-Yue, Wang, Na, Wu, Yi-Zhou
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979651/
https://www.ncbi.nlm.nih.gov/pubmed/21579339
http://dx.doi.org/10.1107/S1600536810017915
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author Lin, Qiu-Yue
Wang, Na
Wu, Yi-Zhou
author_facet Lin, Qiu-Yue
Wang, Na
Wu, Yi-Zhou
author_sort Lin, Qiu-Yue
collection PubMed
description The title polymer, [Zn(3)(C(8)H(8)O(5))(2)(C(3)H(3)N(2))(2)(C(3)H(4)N(2))(2)](n), was formed by the reaction of zinc acetate with imidazole and 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylic anhydride (norcan­tharidine). One of the two crystallographically unique Zn(II) atoms is four-coordinated by three N atoms of three imidazole ligands, two of which are deprotonated, and by one carboxyl­ate O atom of the demethyl­cantharate anion. The second Zn(II) atom is situated on an inversion centre and is six-coordinated by the bridging O atoms of two symmetry-related demethyl­cantharate anions and by four carboxyl­ate O atoms of the corresponding carboxyl­ate groups. The polymeric crystal structure is additionally stabilized by N—H⋯O hydrogen bonding between the imidazole ligands and carboxyl­ate O atoms.
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spelling pubmed-29796512010-12-30 Poly[bis­(1H-imidazole)bis­(μ(2)-1H-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(II)] Lin, Qiu-Yue Wang, Na Wu, Yi-Zhou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title polymer, [Zn(3)(C(8)H(8)O(5))(2)(C(3)H(3)N(2))(2)(C(3)H(4)N(2))(2)](n), was formed by the reaction of zinc acetate with imidazole and 7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxylic anhydride (norcan­tharidine). One of the two crystallographically unique Zn(II) atoms is four-coordinated by three N atoms of three imidazole ligands, two of which are deprotonated, and by one carboxyl­ate O atom of the demethyl­cantharate anion. The second Zn(II) atom is situated on an inversion centre and is six-coordinated by the bridging O atoms of two symmetry-related demethyl­cantharate anions and by four carboxyl­ate O atoms of the corresponding carboxyl­ate groups. The polymeric crystal structure is additionally stabilized by N—H⋯O hydrogen bonding between the imidazole ligands and carboxyl­ate O atoms. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979651/ /pubmed/21579339 http://dx.doi.org/10.1107/S1600536810017915 Text en © Lin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Qiu-Yue
Wang, Na
Wu, Yi-Zhou
Poly[bis­(1H-imidazole)bis­(μ(2)-1H-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(II)]
title Poly[bis­(1H-imidazole)bis­(μ(2)-1H-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(II)]
title_full Poly[bis­(1H-imidazole)bis­(μ(2)-1H-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(II)]
title_fullStr Poly[bis­(1H-imidazole)bis­(μ(2)-1H-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(II)]
title_full_unstemmed Poly[bis­(1H-imidazole)bis­(μ(2)-1H-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(II)]
title_short Poly[bis­(1H-imidazole)bis­(μ(2)-1H-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(II)]
title_sort poly[bis­(1h-imidazole)bis­(μ(2)-1h-imidazolido)bis­(μ(2)-7-oxabicyclo­[2.2.1]heptane-2,3-dicarboxyl­ato)trizinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979651/
https://www.ncbi.nlm.nih.gov/pubmed/21579339
http://dx.doi.org/10.1107/S1600536810017915
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