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Poly[bis(1H-imidazole)bis(μ(2)-1H-imidazolido)bis(μ(2)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)trizinc(II)]
The title polymer, [Zn(3)(C(8)H(8)O(5))(2)(C(3)H(3)N(2))(2)(C(3)H(4)N(2))(2)](n), was formed by the reaction of zinc acetate with imidazole and 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride (norcantharidine). One of the two crystallographically unique Zn(II) atoms is four-coordinated by th...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979651/ https://www.ncbi.nlm.nih.gov/pubmed/21579339 http://dx.doi.org/10.1107/S1600536810017915 |
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author | Lin, Qiu-Yue Wang, Na Wu, Yi-Zhou |
author_facet | Lin, Qiu-Yue Wang, Na Wu, Yi-Zhou |
author_sort | Lin, Qiu-Yue |
collection | PubMed |
description | The title polymer, [Zn(3)(C(8)H(8)O(5))(2)(C(3)H(3)N(2))(2)(C(3)H(4)N(2))(2)](n), was formed by the reaction of zinc acetate with imidazole and 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride (norcantharidine). One of the two crystallographically unique Zn(II) atoms is four-coordinated by three N atoms of three imidazole ligands, two of which are deprotonated, and by one carboxylate O atom of the demethylcantharate anion. The second Zn(II) atom is situated on an inversion centre and is six-coordinated by the bridging O atoms of two symmetry-related demethylcantharate anions and by four carboxylate O atoms of the corresponding carboxylate groups. The polymeric crystal structure is additionally stabilized by N—H⋯O hydrogen bonding between the imidazole ligands and carboxylate O atoms. |
format | Text |
id | pubmed-2979651 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29796512010-12-30 Poly[bis(1H-imidazole)bis(μ(2)-1H-imidazolido)bis(μ(2)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)trizinc(II)] Lin, Qiu-Yue Wang, Na Wu, Yi-Zhou Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title polymer, [Zn(3)(C(8)H(8)O(5))(2)(C(3)H(3)N(2))(2)(C(3)H(4)N(2))(2)](n), was formed by the reaction of zinc acetate with imidazole and 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride (norcantharidine). One of the two crystallographically unique Zn(II) atoms is four-coordinated by three N atoms of three imidazole ligands, two of which are deprotonated, and by one carboxylate O atom of the demethylcantharate anion. The second Zn(II) atom is situated on an inversion centre and is six-coordinated by the bridging O atoms of two symmetry-related demethylcantharate anions and by four carboxylate O atoms of the corresponding carboxylate groups. The polymeric crystal structure is additionally stabilized by N—H⋯O hydrogen bonding between the imidazole ligands and carboxylate O atoms. International Union of Crystallography 2010-05-22 /pmc/articles/PMC2979651/ /pubmed/21579339 http://dx.doi.org/10.1107/S1600536810017915 Text en © Lin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lin, Qiu-Yue Wang, Na Wu, Yi-Zhou Poly[bis(1H-imidazole)bis(μ(2)-1H-imidazolido)bis(μ(2)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)trizinc(II)] |
title | Poly[bis(1H-imidazole)bis(μ(2)-1H-imidazolido)bis(μ(2)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)trizinc(II)] |
title_full | Poly[bis(1H-imidazole)bis(μ(2)-1H-imidazolido)bis(μ(2)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)trizinc(II)] |
title_fullStr | Poly[bis(1H-imidazole)bis(μ(2)-1H-imidazolido)bis(μ(2)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)trizinc(II)] |
title_full_unstemmed | Poly[bis(1H-imidazole)bis(μ(2)-1H-imidazolido)bis(μ(2)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)trizinc(II)] |
title_short | Poly[bis(1H-imidazole)bis(μ(2)-1H-imidazolido)bis(μ(2)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)trizinc(II)] |
title_sort | poly[bis(1h-imidazole)bis(μ(2)-1h-imidazolido)bis(μ(2)-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)trizinc(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979651/ https://www.ncbi.nlm.nih.gov/pubmed/21579339 http://dx.doi.org/10.1107/S1600536810017915 |
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