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(2-Aminopyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))nickel(II) monohydrate
The reaction of Ni(NO(3))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid, NaOH and 2-aminopyrimidine in aqueous solution leads to the formation of the title complex, [Ni(C(7)H(3)NO(4))(C(4)H(5)N(3))(H(2)O)(2)]·H(2)O. The Ni(II) ion is coordinated by one N and two O atoms of the tridentate chelating...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979663/ https://www.ncbi.nlm.nih.gov/pubmed/21579296 http://dx.doi.org/10.1107/S1600536810016843 |
Sumario: | The reaction of Ni(NO(3))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid, NaOH and 2-aminopyrimidine in aqueous solution leads to the formation of the title complex, [Ni(C(7)H(3)NO(4))(C(4)H(5)N(3))(H(2)O)(2)]·H(2)O. The Ni(II) ion is coordinated by one N and two O atoms of the tridentate chelating pyridine-2,6-dicarboxylate anion, one heterocyclic N atom of the 2-aminopyrimidine ligand, and two water molecules. The resulting geometry for the [NiN(2)O(4)] coordination environment can be described as distorted octahedral. One uncoordinated water molecule completes the asymmetric unit. Extensive O—H⋯O and N—H⋯O hydrogen-bonding interactions between the NH(2) group of 2-aminopyrimidine, carboxylate groups, and coordinated and uncoordinated water molecules contribute to the formation of a three-dimensional supramolecular structure. |
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