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(2-Aminopyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))nickel(II) monohydrate
The reaction of Ni(NO(3))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid, NaOH and 2-aminopyrimidine in aqueous solution leads to the formation of the title complex, [Ni(C(7)H(3)NO(4))(C(4)H(5)N(3))(H(2)O)(2)]·H(2)O. The Ni(II) ion is coordinated by one N and two O atoms of the tridentate chelating...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979663/ https://www.ncbi.nlm.nih.gov/pubmed/21579296 http://dx.doi.org/10.1107/S1600536810016843 |
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author | Tabatabaee, Masoumeh |
author_facet | Tabatabaee, Masoumeh |
author_sort | Tabatabaee, Masoumeh |
collection | PubMed |
description | The reaction of Ni(NO(3))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid, NaOH and 2-aminopyrimidine in aqueous solution leads to the formation of the title complex, [Ni(C(7)H(3)NO(4))(C(4)H(5)N(3))(H(2)O)(2)]·H(2)O. The Ni(II) ion is coordinated by one N and two O atoms of the tridentate chelating pyridine-2,6-dicarboxylate anion, one heterocyclic N atom of the 2-aminopyrimidine ligand, and two water molecules. The resulting geometry for the [NiN(2)O(4)] coordination environment can be described as distorted octahedral. One uncoordinated water molecule completes the asymmetric unit. Extensive O—H⋯O and N—H⋯O hydrogen-bonding interactions between the NH(2) group of 2-aminopyrimidine, carboxylate groups, and coordinated and uncoordinated water molecules contribute to the formation of a three-dimensional supramolecular structure. |
format | Text |
id | pubmed-2979663 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29796632010-12-30 (2-Aminopyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))nickel(II) monohydrate Tabatabaee, Masoumeh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of Ni(NO(3))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid, NaOH and 2-aminopyrimidine in aqueous solution leads to the formation of the title complex, [Ni(C(7)H(3)NO(4))(C(4)H(5)N(3))(H(2)O)(2)]·H(2)O. The Ni(II) ion is coordinated by one N and two O atoms of the tridentate chelating pyridine-2,6-dicarboxylate anion, one heterocyclic N atom of the 2-aminopyrimidine ligand, and two water molecules. The resulting geometry for the [NiN(2)O(4)] coordination environment can be described as distorted octahedral. One uncoordinated water molecule completes the asymmetric unit. Extensive O—H⋯O and N—H⋯O hydrogen-bonding interactions between the NH(2) group of 2-aminopyrimidine, carboxylate groups, and coordinated and uncoordinated water molecules contribute to the formation of a three-dimensional supramolecular structure. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979663/ /pubmed/21579296 http://dx.doi.org/10.1107/S1600536810016843 Text en © Masoumeh Tabatabaee 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Tabatabaee, Masoumeh (2-Aminopyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxylato-κ(3) O (2),N,O (6))nickel(II) monohydrate |
title | (2-Aminopyrimidine-κN
(1))diaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))nickel(II) monohydrate |
title_full | (2-Aminopyrimidine-κN
(1))diaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))nickel(II) monohydrate |
title_fullStr | (2-Aminopyrimidine-κN
(1))diaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))nickel(II) monohydrate |
title_full_unstemmed | (2-Aminopyrimidine-κN
(1))diaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))nickel(II) monohydrate |
title_short | (2-Aminopyrimidine-κN
(1))diaqua(pyridine-2,6-dicarboxylato-κ(3)
O
(2),N,O
(6))nickel(II) monohydrate |
title_sort | (2-aminopyrimidine-κn
(1))diaqua(pyridine-2,6-dicarboxylato-κ(3)
o
(2),n,o
(6))nickel(ii) monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979663/ https://www.ncbi.nlm.nih.gov/pubmed/21579296 http://dx.doi.org/10.1107/S1600536810016843 |
work_keys_str_mv | AT tabatabaeemasoumeh 2aminopyrimidinekn1diaquapyridine26dicarboxylatok3o2no6nickeliimonohydrate |