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(2-Amino­pyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))­nickel(II) monohydrate

The reaction of Ni(NO(3))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid, NaOH and 2-amino­pyrimidine in aqueous solution leads to the formation of the title complex, [Ni(C(7)H(3)NO(4))(C(4)H(5)N(3))(H(2)O)(2)]·H(2)O. The Ni(II) ion is coordinated by one N and two O atoms of the tridentate chelating...

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Autor principal: Tabatabaee, Masoumeh
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979663/
https://www.ncbi.nlm.nih.gov/pubmed/21579296
http://dx.doi.org/10.1107/S1600536810016843
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author Tabatabaee, Masoumeh
author_facet Tabatabaee, Masoumeh
author_sort Tabatabaee, Masoumeh
collection PubMed
description The reaction of Ni(NO(3))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid, NaOH and 2-amino­pyrimidine in aqueous solution leads to the formation of the title complex, [Ni(C(7)H(3)NO(4))(C(4)H(5)N(3))(H(2)O)(2)]·H(2)O. The Ni(II) ion is coordinated by one N and two O atoms of the tridentate chelating pyridine-2,6-dicarboxyl­ate anion, one heterocyclic N atom of the 2-amino­pyrimidine ligand, and two water mol­ecules. The resulting geometry for the [NiN(2)O(4)] coordination environment can be described as distorted octa­hedral. One uncoord­inated water mol­ecule completes the asymmetric unit. Extensive O—H⋯O and N—H⋯O hydrogen-bonding inter­actions between the NH(2) group of 2-amino­pyrimidine, carboxyl­ate groups, and coordinated and uncoordinated water mol­ecules contribute to the formation of a three-dimensional supra­molecular structure.
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spelling pubmed-29796632010-12-30 (2-Amino­pyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))­nickel(II) monohydrate Tabatabaee, Masoumeh Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of Ni(NO(3))(2)·6H(2)O with pyridine-2,6-dicarboxylic acid, NaOH and 2-amino­pyrimidine in aqueous solution leads to the formation of the title complex, [Ni(C(7)H(3)NO(4))(C(4)H(5)N(3))(H(2)O)(2)]·H(2)O. The Ni(II) ion is coordinated by one N and two O atoms of the tridentate chelating pyridine-2,6-dicarboxyl­ate anion, one heterocyclic N atom of the 2-amino­pyrimidine ligand, and two water mol­ecules. The resulting geometry for the [NiN(2)O(4)] coordination environment can be described as distorted octa­hedral. One uncoord­inated water mol­ecule completes the asymmetric unit. Extensive O—H⋯O and N—H⋯O hydrogen-bonding inter­actions between the NH(2) group of 2-amino­pyrimidine, carboxyl­ate groups, and coordinated and uncoordinated water mol­ecules contribute to the formation of a three-dimensional supra­molecular structure. International Union of Crystallography 2010-05-15 /pmc/articles/PMC2979663/ /pubmed/21579296 http://dx.doi.org/10.1107/S1600536810016843 Text en © Masoumeh Tabatabaee 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tabatabaee, Masoumeh
(2-Amino­pyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))­nickel(II) monohydrate
title (2-Amino­pyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))­nickel(II) monohydrate
title_full (2-Amino­pyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))­nickel(II) monohydrate
title_fullStr (2-Amino­pyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))­nickel(II) monohydrate
title_full_unstemmed (2-Amino­pyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))­nickel(II) monohydrate
title_short (2-Amino­pyrimidine-κN (1))diaqua(pyridine-2,6-dicarboxyl­ato-κ(3) O (2),N,O (6))­nickel(II) monohydrate
title_sort (2-amino­pyrimidine-κn (1))diaqua(pyridine-2,6-dicarboxyl­ato-κ(3) o (2),n,o (6))­nickel(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979663/
https://www.ncbi.nlm.nih.gov/pubmed/21579296
http://dx.doi.org/10.1107/S1600536810016843
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