1-Bromo-2,3,6-trichloro-4,5-dimethoxy­benzene

The halogen atoms of the title compound, C(8)H(6)BrCl(3)O(2), are located within the plane of the benzene ring [r.m.s. deviation = 0.036 (11) Å]. The two meth­oxy groups are twisted out of this plane, with dihedral angles of 84.7 (3) and 68.5 (3)°, and point in opposite directions. The structure is...

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Detalles Bibliográficos
Autores principales: Song, Yang, Parkin, Sean, Lehmler, Hans-Joachim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979667/
https://www.ncbi.nlm.nih.gov/pubmed/21579894
http://dx.doi.org/10.1107/S1600536810002977
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author Song, Yang
Parkin, Sean
Lehmler, Hans-Joachim
author_facet Song, Yang
Parkin, Sean
Lehmler, Hans-Joachim
author_sort Song, Yang
collection PubMed
description The halogen atoms of the title compound, C(8)H(6)BrCl(3)O(2), are located within the plane of the benzene ring [r.m.s. deviation = 0.036 (11) Å]. The two meth­oxy groups are twisted out of this plane, with dihedral angles of 84.7 (3) and 68.5 (3)°, and point in opposite directions. The structure is disordered by a non-crystallographic twofold rotation which superimposes Cl and Br at two of the halogen sites. The refined occupancies for the major and minor components are 0.517 (2) and 0.483 (2).
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spelling pubmed-29796672010-12-30 1-Bromo-2,3,6-trichloro-4,5-dimethoxy­benzene Song, Yang Parkin, Sean Lehmler, Hans-Joachim Acta Crystallogr Sect E Struct Rep Online Organic Papers The halogen atoms of the title compound, C(8)H(6)BrCl(3)O(2), are located within the plane of the benzene ring [r.m.s. deviation = 0.036 (11) Å]. The two meth­oxy groups are twisted out of this plane, with dihedral angles of 84.7 (3) and 68.5 (3)°, and point in opposite directions. The structure is disordered by a non-crystallographic twofold rotation which superimposes Cl and Br at two of the halogen sites. The refined occupancies for the major and minor components are 0.517 (2) and 0.483 (2). International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979667/ /pubmed/21579894 http://dx.doi.org/10.1107/S1600536810002977 Text en © Song et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Song, Yang
Parkin, Sean
Lehmler, Hans-Joachim
1-Bromo-2,3,6-trichloro-4,5-dimethoxy­benzene
title 1-Bromo-2,3,6-trichloro-4,5-dimethoxy­benzene
title_full 1-Bromo-2,3,6-trichloro-4,5-dimethoxy­benzene
title_fullStr 1-Bromo-2,3,6-trichloro-4,5-dimethoxy­benzene
title_full_unstemmed 1-Bromo-2,3,6-trichloro-4,5-dimethoxy­benzene
title_short 1-Bromo-2,3,6-trichloro-4,5-dimethoxy­benzene
title_sort 1-bromo-2,3,6-trichloro-4,5-dimethoxy­benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979667/
https://www.ncbi.nlm.nih.gov/pubmed/21579894
http://dx.doi.org/10.1107/S1600536810002977
work_keys_str_mv AT songyang 1bromo236trichloro45dimethoxybenzene
AT parkinsean 1bromo236trichloro45dimethoxybenzene
AT lehmlerhansjoachim 1bromo236trichloro45dimethoxybenzene

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