[6-(4-Bromo­phen­yl)-2,2′-bipyridine-κ(2) N,N′](tricyclo­hexyl­phosphine-κP)copper(I) tetra­fluoridoborate

In the title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(33)P)]BF(4), the Cu(I) atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromo­phen­yl)-2,2′-bipyridine ligand and a P atom from the tricyclo­hexyl­phosphine ligand. In addition, a weak anion⋯Cu(I) inter­a...

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Detalles Bibliográficos
Autor principal: Peng, Xi-Long
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979668/
https://www.ncbi.nlm.nih.gov/pubmed/21579680
http://dx.doi.org/10.1107/S1600536810002965
Descripción
Sumario:In the title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(33)P)]BF(4), the Cu(I) atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromo­phen­yl)-2,2′-bipyridine ligand and a P atom from the tricyclo­hexyl­phosphine ligand. In addition, a weak anion⋯Cu(I) inter­action with a nearest F⋯Cu separation of 2.696 (5) Å is found.

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