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[6-(4-Bromophenyl)-2,2′-bipyridine-κ(2) N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate
In the title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(33)P)]BF(4), the Cu(I) atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromophenyl)-2,2′-bipyridine ligand and a P atom from the tricyclohexylphosphine ligand. In addition, a weak anion⋯Cu(I) intera...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979668/ https://www.ncbi.nlm.nih.gov/pubmed/21579680 http://dx.doi.org/10.1107/S1600536810002965 |
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author | Peng, Xi-Long |
author_facet | Peng, Xi-Long |
author_sort | Peng, Xi-Long |
collection | PubMed |
description | In the title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(33)P)]BF(4), the Cu(I) atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromophenyl)-2,2′-bipyridine ligand and a P atom from the tricyclohexylphosphine ligand. In addition, a weak anion⋯Cu(I) interaction with a nearest F⋯Cu separation of 2.696 (5) Å is found. |
format | Text |
id | pubmed-2979668 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29796682010-12-30 [6-(4-Bromophenyl)-2,2′-bipyridine-κ(2) N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate Peng, Xi-Long Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(16)H(11)BrN(2))(C(18)H(33)P)]BF(4), the Cu(I) atom is three-coordinated in a distorted trigonal configuration by two N atoms from the 6-(4-bromophenyl)-2,2′-bipyridine ligand and a P atom from the tricyclohexylphosphine ligand. In addition, a weak anion⋯Cu(I) interaction with a nearest F⋯Cu separation of 2.696 (5) Å is found. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979668/ /pubmed/21579680 http://dx.doi.org/10.1107/S1600536810002965 Text en © Xi-Long Peng 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Peng, Xi-Long [6-(4-Bromophenyl)-2,2′-bipyridine-κ(2) N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate |
title | [6-(4-Bromophenyl)-2,2′-bipyridine-κ(2)
N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate |
title_full | [6-(4-Bromophenyl)-2,2′-bipyridine-κ(2)
N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate |
title_fullStr | [6-(4-Bromophenyl)-2,2′-bipyridine-κ(2)
N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate |
title_full_unstemmed | [6-(4-Bromophenyl)-2,2′-bipyridine-κ(2)
N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate |
title_short | [6-(4-Bromophenyl)-2,2′-bipyridine-κ(2)
N,N′](tricyclohexylphosphine-κP)copper(I) tetrafluoridoborate |
title_sort | [6-(4-bromophenyl)-2,2′-bipyridine-κ(2)
n,n′](tricyclohexylphosphine-κp)copper(i) tetrafluoridoborate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979668/ https://www.ncbi.nlm.nih.gov/pubmed/21579680 http://dx.doi.org/10.1107/S1600536810002965 |
work_keys_str_mv | AT pengxilong 64bromophenyl22bipyridinek2nntricyclohexylphosphinekpcopperitetrafluoridoborate |