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Bis{2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide}copper(I) tetra­fluoridoborate

The title complex, [Cu(C(14)H(14)N(2)O(2))(2)]BF(4), is a monomeric copper(I) species with linear two-coordinate geometry around the Cu(I) atom. The asymmetric unit contains two half-cations that sit on crystallographic twofold rotation axes. The selected crystal was non-merohedrally twinned by a tw...

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Detalles Bibliográficos
Autores principales: Wang, Zhaodong, Powell, Douglas R., Houser, Robert P.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979673/
https://www.ncbi.nlm.nih.gov/pubmed/21579646
http://dx.doi.org/10.1107/S1600536810001364
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author Wang, Zhaodong
Powell, Douglas R.
Houser, Robert P.
author_facet Wang, Zhaodong
Powell, Douglas R.
Houser, Robert P.
author_sort Wang, Zhaodong
collection PubMed
description The title complex, [Cu(C(14)H(14)N(2)O(2))(2)]BF(4), is a monomeric copper(I) species with linear two-coordinate geometry around the Cu(I) atom. The asymmetric unit contains two half-cations that sit on crystallographic twofold rotation axes. The selected crystal was non-merohedrally twinned by a twofold rotation about an axis normal to the (100) family of planes. The ratio of the twin components refined to 0.4123 (6). Two 2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide ligands coordinate to each Cu(I) atom via the pyridyl N atom. Intra­molecular hydrogen bonding between the phenol OH groups and the amide O atoms imparts rigidity and planarity to the non-coordinating end of the ligand. The cationic complex is linked to the BF(4) (−) anions via hydrogen bonding between the amide NH groups in the cations and BF(4) (−) anions.
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spelling pubmed-29796732010-12-30 Bis{2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide}copper(I) tetra­fluoridoborate Wang, Zhaodong Powell, Douglas R. Houser, Robert P. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu(C(14)H(14)N(2)O(2))(2)]BF(4), is a monomeric copper(I) species with linear two-coordinate geometry around the Cu(I) atom. The asymmetric unit contains two half-cations that sit on crystallographic twofold rotation axes. The selected crystal was non-merohedrally twinned by a twofold rotation about an axis normal to the (100) family of planes. The ratio of the twin components refined to 0.4123 (6). Two 2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide ligands coordinate to each Cu(I) atom via the pyridyl N atom. Intra­molecular hydrogen bonding between the phenol OH groups and the amide O atoms imparts rigidity and planarity to the non-coordinating end of the ligand. The cationic complex is linked to the BF(4) (−) anions via hydrogen bonding between the amide NH groups in the cations and BF(4) (−) anions. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979673/ /pubmed/21579646 http://dx.doi.org/10.1107/S1600536810001364 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Zhaodong
Powell, Douglas R.
Houser, Robert P.
Bis{2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide}copper(I) tetra­fluoridoborate
title Bis{2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide}copper(I) tetra­fluoridoborate
title_full Bis{2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide}copper(I) tetra­fluoridoborate
title_fullStr Bis{2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide}copper(I) tetra­fluoridoborate
title_full_unstemmed Bis{2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide}copper(I) tetra­fluoridoborate
title_short Bis{2-hydr­oxy-N-[2-(2-pyrid­yl)eth­yl]benzamide}copper(I) tetra­fluoridoborate
title_sort bis{2-hydr­oxy-n-[2-(2-pyrid­yl)eth­yl]benzamide}copper(i) tetra­fluoridoborate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979673/
https://www.ncbi.nlm.nih.gov/pubmed/21579646
http://dx.doi.org/10.1107/S1600536810001364
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