2-(2-Naphth­yl)-1,3-dioxane

The title compound, C(14)H(14)O(2), crystallizes in the chiral monoclinic space group P2(1). This acetal is composed of a planar naphthalene ring with a 1,3-dioxane ring substituent, which has a chair conformation. In the crystal structure, symmetry-related mol­ecules are connected via a weak C—H⋯O...

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Detalles Bibliográficos
Autores principales: Thevenet, Damien, Neier, Reinhard, Stoeckli-Evans, Helen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979677/
https://www.ncbi.nlm.nih.gov/pubmed/21579883
http://dx.doi.org/10.1107/S1600536810000644
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author Thevenet, Damien
Neier, Reinhard
Stoeckli-Evans, Helen
author_facet Thevenet, Damien
Neier, Reinhard
Stoeckli-Evans, Helen
author_sort Thevenet, Damien
collection PubMed
description The title compound, C(14)H(14)O(2), crystallizes in the chiral monoclinic space group P2(1). This acetal is composed of a planar naphthalene ring with a 1,3-dioxane ring substituent, which has a chair conformation. In the crystal structure, symmetry-related mol­ecules are connected via a weak C—H⋯O inter­action to form a helical chain propagating in [010]. While there are no π–π stacking inter­actions present, there are weak C—H⋯π inter­actions involving the naphthalene aromatic rings, which link the helical chains to form a two-dimensional network in the (011) plane.
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spelling pubmed-29796772010-12-30 2-(2-Naphth­yl)-1,3-dioxane Thevenet, Damien Neier, Reinhard Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(14)H(14)O(2), crystallizes in the chiral monoclinic space group P2(1). This acetal is composed of a planar naphthalene ring with a 1,3-dioxane ring substituent, which has a chair conformation. In the crystal structure, symmetry-related mol­ecules are connected via a weak C—H⋯O inter­action to form a helical chain propagating in [010]. While there are no π–π stacking inter­actions present, there are weak C—H⋯π inter­actions involving the naphthalene aromatic rings, which link the helical chains to form a two-dimensional network in the (011) plane. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979677/ /pubmed/21579883 http://dx.doi.org/10.1107/S1600536810000644 Text en © Thevenet et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Thevenet, Damien
Neier, Reinhard
Stoeckli-Evans, Helen
2-(2-Naphth­yl)-1,3-dioxane
title 2-(2-Naphth­yl)-1,3-dioxane
title_full 2-(2-Naphth­yl)-1,3-dioxane
title_fullStr 2-(2-Naphth­yl)-1,3-dioxane
title_full_unstemmed 2-(2-Naphth­yl)-1,3-dioxane
title_short 2-(2-Naphth­yl)-1,3-dioxane
title_sort 2-(2-naphth­yl)-1,3-dioxane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979677/
https://www.ncbi.nlm.nih.gov/pubmed/21579883
http://dx.doi.org/10.1107/S1600536810000644
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AT neierreinhard 22naphthyl13dioxane
AT stoecklievanshelen 22naphthyl13dioxane

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