Cargando…

Bis(2,2′-bipyridyl-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO (1);κ(2) O (1),O (1′)-cadmium(II) methanol solvate

The title compound, [Cd(C(7)H(5)O(3))(2)(C(10)H(8)N(2))(2)]·CH(3)OH, contains one monomeric seven-coordinate cadmium complex and one methanol solvate mol­ecule. The Cd(II) atom is coordinated to two 2,2′-bipyridyl ligands via the N atoms and to two salicylate anions (Hsal(−)) via the carboxyl­ate O...

Descripción completa

Detalles Bibliográficos
Autores principales: Benrabah, Rymel, Viossat, Bernard, Tomas, Alain, Lemoine, Pascale
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979681/
https://www.ncbi.nlm.nih.gov/pubmed/21579632
http://dx.doi.org/10.1107/S1600536809054610
_version_ 1782191471883976704
author Benrabah, Rymel
Viossat, Bernard
Tomas, Alain
Lemoine, Pascale
author_facet Benrabah, Rymel
Viossat, Bernard
Tomas, Alain
Lemoine, Pascale
author_sort Benrabah, Rymel
collection PubMed
description The title compound, [Cd(C(7)H(5)O(3))(2)(C(10)H(8)N(2))(2)]·CH(3)OH, contains one monomeric seven-coordinate cadmium complex and one methanol solvate mol­ecule. The Cd(II) atom is coordinated to two 2,2′-bipyridyl ligands via the N atoms and to two salicylate anions (Hsal(−)) via the carboxyl­ate O atoms, which act as monodentate ligand for the one and bidentate ligand for the second. The Cd(II) atom exhibits a {6 + 1} environment, approximately described as a distorted capped octa­hedron with the apical positions occupied by one of the two N atoms belonging to one bipyridyl ligand and one of the two carboxyl­ate O atoms from the monodentate Hsal(−) ligand. Two intra­molecular six-membered hydrogen-bonded rings are present, generated from inter­actions between the carboxyl­ate and hydr­oxy groups of the salicylate ligands. There is one inter­molecular hydrogen-bonding inter­action involving the methanol solvent mol­ecule and the carboxyl­ate group from the monodentate Hsal(−) ligand. The crystal packing is governed by π–π stacking inter­actions [centroid–centroid distance = 3.783 (4) Å] which occur between bipyridyl ligands, by C—H⋯O and C—H⋯π inter­actions and by numerous van der Waals contacts.
format Text
id pubmed-2979681
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29796812010-12-30 Bis(2,2′-bipyridyl-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO (1);κ(2) O (1),O (1′)-cadmium(II) methanol solvate Benrabah, Rymel Viossat, Bernard Tomas, Alain Lemoine, Pascale Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Cd(C(7)H(5)O(3))(2)(C(10)H(8)N(2))(2)]·CH(3)OH, contains one monomeric seven-coordinate cadmium complex and one methanol solvate mol­ecule. The Cd(II) atom is coordinated to two 2,2′-bipyridyl ligands via the N atoms and to two salicylate anions (Hsal(−)) via the carboxyl­ate O atoms, which act as monodentate ligand for the one and bidentate ligand for the second. The Cd(II) atom exhibits a {6 + 1} environment, approximately described as a distorted capped octa­hedron with the apical positions occupied by one of the two N atoms belonging to one bipyridyl ligand and one of the two carboxyl­ate O atoms from the monodentate Hsal(−) ligand. Two intra­molecular six-membered hydrogen-bonded rings are present, generated from inter­actions between the carboxyl­ate and hydr­oxy groups of the salicylate ligands. There is one inter­molecular hydrogen-bonding inter­action involving the methanol solvent mol­ecule and the carboxyl­ate group from the monodentate Hsal(−) ligand. The crystal packing is governed by π–π stacking inter­actions [centroid–centroid distance = 3.783 (4) Å] which occur between bipyridyl ligands, by C—H⋯O and C—H⋯π inter­actions and by numerous van der Waals contacts. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979681/ /pubmed/21579632 http://dx.doi.org/10.1107/S1600536809054610 Text en © Rymel et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Benrabah, Rymel
Viossat, Bernard
Tomas, Alain
Lemoine, Pascale
Bis(2,2′-bipyridyl-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO (1);κ(2) O (1),O (1′)-cadmium(II) methanol solvate
title Bis(2,2′-bipyridyl-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO (1);κ(2) O (1),O (1′)-cadmium(II) methanol solvate
title_full Bis(2,2′-bipyridyl-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO (1);κ(2) O (1),O (1′)-cadmium(II) methanol solvate
title_fullStr Bis(2,2′-bipyridyl-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO (1);κ(2) O (1),O (1′)-cadmium(II) methanol solvate
title_full_unstemmed Bis(2,2′-bipyridyl-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO (1);κ(2) O (1),O (1′)-cadmium(II) methanol solvate
title_short Bis(2,2′-bipyridyl-κ(2) N,N′)bis­(2-hydroxy­benzoato)-κO (1);κ(2) O (1),O (1′)-cadmium(II) methanol solvate
title_sort bis(2,2′-bipyridyl-κ(2) n,n′)bis­(2-hydroxy­benzoato)-κo (1);κ(2) o (1),o (1′)-cadmium(ii) methanol solvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979681/
https://www.ncbi.nlm.nih.gov/pubmed/21579632
http://dx.doi.org/10.1107/S1600536809054610
work_keys_str_mv AT benrabahrymel bis22bipyridylk2nnbis2hydroxybenzoatoko1k2o1o1cadmiumiimethanolsolvate
AT viossatbernard bis22bipyridylk2nnbis2hydroxybenzoatoko1k2o1o1cadmiumiimethanolsolvate
AT tomasalain bis22bipyridylk2nnbis2hydroxybenzoatoko1k2o1o1cadmiumiimethanolsolvate
AT lemoinepascale bis22bipyridylk2nnbis2hydroxybenzoatoko1k2o1o1cadmiumiimethanolsolvate