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Dipotassium diaquabis(methylenediphosphonato-κ(2) O,O′)cobaltate(II)
In the title complex, K(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], the asymmetric unit contains two K(+) cations and two half-anions in which the Co atoms lie on inversion centers. The Co(II) ions assume an octahedral CoO(6) coordination geometry. In the crystal, a three-dimensional network is formed thro...
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979685/ https://www.ncbi.nlm.nih.gov/pubmed/21579634 http://dx.doi.org/10.1107/S160053680905106X |
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| author | Visser, H.G. Venter, J.A. Van der Merwe, K.A. |
| author_facet | Visser, H.G. Venter, J.A. Van der Merwe, K.A. |
| author_sort | Visser, H.G. |
| collection | PubMed |
| description | In the title complex, K(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], the asymmetric unit contains two K(+) cations and two half-anions in which the Co atoms lie on inversion centers. The Co(II) ions assume an octahedral CoO(6) coordination geometry. In the crystal, a three-dimensional network is formed through O—H⋯O hydrogen-bond interactions as well as intermolecular interactions between the K(+) cations and neighbouring O atoms. |
| format | Text |
| id | pubmed-2979685 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29796852010-12-30 Dipotassium diaquabis(methylenediphosphonato-κ(2) O,O′)cobaltate(II) Visser, H.G. Venter, J.A. Van der Merwe, K.A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, K(2)[Co(CH(4)O(6)P(2))(2)(H(2)O)(2)], the asymmetric unit contains two K(+) cations and two half-anions in which the Co atoms lie on inversion centers. The Co(II) ions assume an octahedral CoO(6) coordination geometry. In the crystal, a three-dimensional network is formed through O—H⋯O hydrogen-bond interactions as well as intermolecular interactions between the K(+) cations and neighbouring O atoms. International Union of Crystallography 2010-01-16 /pmc/articles/PMC2979685/ /pubmed/21579634 http://dx.doi.org/10.1107/S160053680905106X Text en © Visser et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Visser, H.G. Venter, J.A. Van der Merwe, K.A. Dipotassium diaquabis(methylenediphosphonato-κ(2) O,O′)cobaltate(II) |
| title | Dipotassium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_full | Dipotassium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_fullStr | Dipotassium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_full_unstemmed | Dipotassium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_short | Dipotassium diaquabis(methylenediphosphonato-κ(2)
O,O′)cobaltate(II) |
| title_sort | dipotassium diaquabis(methylenediphosphonato-κ(2)
o,o′)cobaltate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979685/ https://www.ncbi.nlm.nih.gov/pubmed/21579634 http://dx.doi.org/10.1107/S160053680905106X |
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