Bis{2-eth­oxy-6-[2-(methyl­ammonio)ethyl­imino­meth­yl]phenolato}thio­cyanato­zinc(II) nitrate

In the title compound, [Zn(NCS)(C(12)H(18)N(2)O(2))(2)]NO(3), the Zn(II) ion is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands and is also coordinated by the N atom of a thio­cyanate ligand, giving a distorted trigonal-bipyramidal geometry. Intra­molecular N—...

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Detalles Bibliográficos
Autores principales: Wang, Chen-Yi, Han, Zhi-Ping, Wu, Xiang, Yuan, Cai-Jun, Zhou, Jun-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979686/
https://www.ncbi.nlm.nih.gov/pubmed/21579607
http://dx.doi.org/10.1107/S1600536810000036
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author Wang, Chen-Yi
Han, Zhi-Ping
Wu, Xiang
Yuan, Cai-Jun
Zhou, Jun-Bo
author_facet Wang, Chen-Yi
Han, Zhi-Ping
Wu, Xiang
Yuan, Cai-Jun
Zhou, Jun-Bo
author_sort Wang, Chen-Yi
collection PubMed
description In the title compound, [Zn(NCS)(C(12)H(18)N(2)O(2))(2)]NO(3), the Zn(II) ion is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands and is also coordinated by the N atom of a thio­cyanate ligand, giving a distorted trigonal-bipyramidal geometry. Intra­molecular N—H⋯O hydrogen bonds are observed in the complex cation. The nitrate anions are linked to the complex cations through N—H⋯O hydrogen bonds.
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spelling pubmed-29796862010-12-30 Bis{2-eth­oxy-6-[2-(methyl­ammonio)ethyl­imino­meth­yl]phenolato}thio­cyanato­zinc(II) nitrate Wang, Chen-Yi Han, Zhi-Ping Wu, Xiang Yuan, Cai-Jun Zhou, Jun-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(NCS)(C(12)H(18)N(2)O(2))(2)]NO(3), the Zn(II) ion is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands and is also coordinated by the N atom of a thio­cyanate ligand, giving a distorted trigonal-bipyramidal geometry. Intra­molecular N—H⋯O hydrogen bonds are observed in the complex cation. The nitrate anions are linked to the complex cations through N—H⋯O hydrogen bonds. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979686/ /pubmed/21579607 http://dx.doi.org/10.1107/S1600536810000036 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chen-Yi
Han, Zhi-Ping
Wu, Xiang
Yuan, Cai-Jun
Zhou, Jun-Bo
Bis{2-eth­oxy-6-[2-(methyl­ammonio)ethyl­imino­meth­yl]phenolato}thio­cyanato­zinc(II) nitrate
title Bis{2-eth­oxy-6-[2-(methyl­ammonio)ethyl­imino­meth­yl]phenolato}thio­cyanato­zinc(II) nitrate
title_full Bis{2-eth­oxy-6-[2-(methyl­ammonio)ethyl­imino­meth­yl]phenolato}thio­cyanato­zinc(II) nitrate
title_fullStr Bis{2-eth­oxy-6-[2-(methyl­ammonio)ethyl­imino­meth­yl]phenolato}thio­cyanato­zinc(II) nitrate
title_full_unstemmed Bis{2-eth­oxy-6-[2-(methyl­ammonio)ethyl­imino­meth­yl]phenolato}thio­cyanato­zinc(II) nitrate
title_short Bis{2-eth­oxy-6-[2-(methyl­ammonio)ethyl­imino­meth­yl]phenolato}thio­cyanato­zinc(II) nitrate
title_sort bis{2-eth­oxy-6-[2-(methyl­ammonio)ethyl­imino­meth­yl]phenolato}thio­cyanato­zinc(ii) nitrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979686/
https://www.ncbi.nlm.nih.gov/pubmed/21579607
http://dx.doi.org/10.1107/S1600536810000036
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