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N,N′-Bis[(E)-2-fluorobenzylidene]-1-(2-fluorophenyl)methanediamine
In the title compound, C(21)H(15)F(3)N(2), the benzene ring bonded to the central C atom forms dihedral angles of 77.5 (7) and 89.0 (5)°, respectively, with the remaining two benzene rings. Weak intermolecular C—H⋯F hydrogen bonds link the molecules into chains propagated in [101]. The crystal pac...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979692/ https://www.ncbi.nlm.nih.gov/pubmed/21579838 http://dx.doi.org/10.1107/S1600536810001984 |
Sumario: | In the title compound, C(21)H(15)F(3)N(2), the benzene ring bonded to the central C atom forms dihedral angles of 77.5 (7) and 89.0 (5)°, respectively, with the remaining two benzene rings. Weak intermolecular C—H⋯F hydrogen bonds link the molecules into chains propagated in [101]. The crystal packing exhibits weak π–π interactions as evidenced by relatively short distances between the centroids of the aromatic rings [3.820 (7) and 3.971 (5) Å]. A MOPAC PM3 optimization of the molecular geometry in vacuo supports a suggestion that intermolecular forces have a significnt influence on the molecular conformation in the crystal. |
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