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Redetermination of diammonium thiomolybdate
In contrast to the previous structure determinations of the title structure, (NH(4))(2)[MoS(4)], the present determination at 173 K localized the positions of the H atoms. The title structure belongs to the β-K(2)SO(4) family and all the ions are located on crystallographic mirror planes. The ions a...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979694/ https://www.ncbi.nlm.nih.gov/pubmed/21579587 http://dx.doi.org/10.1107/S1600536810003016 |
| Sumario: | In contrast to the previous structure determinations of the title structure, (NH(4))(2)[MoS(4)], the present determination at 173 K localized the positions of the H atoms. The title structure belongs to the β-K(2)SO(4) family and all the ions are located on crystallographic mirror planes. The ions are held together by N—H⋯S hydrogen bonds (some of which are bifurcated), forming a three-dimensional network. One of the N atoms has nine contacts to the S atoms shorter than 4 Å, and the other has ten. |
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