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Bis(1,5-diphenylcarbazonato)dimethanolcobalt(II)
The structure of the title compound, [Co(C(13)H(11)N(4)O)(2)(CH(3)OH)(2)], is a mononuclear six-coordinated octahedral cobalt(II) complex of C (i) molecular symmetry. The Co(II) ion is coordinated by two N atoms and two O atoms from two 1,5-biphenylcarbazide ligands, and two O atoms from two meth...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979696/ https://www.ncbi.nlm.nih.gov/pubmed/21579603 http://dx.doi.org/10.1107/S1600536809055305 |
Sumario: | The structure of the title compound, [Co(C(13)H(11)N(4)O)(2)(CH(3)OH)(2)], is a mononuclear six-coordinated octahedral cobalt(II) complex of C (i) molecular symmetry. The Co(II) ion is coordinated by two N atoms and two O atoms from two 1,5-biphenylcarbazide ligands, and two O atoms from two methanol molecules. Two diphenylcarbazidate ligands and the central Co(II) ion form the basal plane, with the two methanol molecules located in axial positions. The crystal packing is defined by bifurcated O—H⋯N hydrogen bonding and intramolecular N—H⋯O interactions. |
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