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[Diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(II)

In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyl­dipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordi...

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Detalles Bibliográficos
Autores principales: Shaw, Janet L., Noll, Bruce C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979699/
https://www.ncbi.nlm.nih.gov/pubmed/21579621
http://dx.doi.org/10.1107/S1600536810000565
Descripción
Sumario:In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyl­dipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordination at the Co(II) center is best described as distorted octa­hedral with two NO(3) (−) anions serving as bidentate ligands for charge balance. The dihedral angle between the mean planes of the two nitrate rings is 85.0 (1)° and that between the mean planes of the two phenyl rings is 73.7 (1)°. The crystal structure is stabilized by weak inter­molecular C—H⋯O and intra­molecular C—H⋯N hydrogen-bond inter­actions.