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[Diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(II)
In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyldipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordi...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979699/ https://www.ncbi.nlm.nih.gov/pubmed/21579621 http://dx.doi.org/10.1107/S1600536810000565 |
Sumario: | In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyldipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordination at the Co(II) center is best described as distorted octahedral with two NO(3) (−) anions serving as bidentate ligands for charge balance. The dihedral angle between the mean planes of the two nitrate rings is 85.0 (1)° and that between the mean planes of the two phenyl rings is 73.7 (1)°. The crystal structure is stabilized by weak intermolecular C—H⋯O and intramolecular C—H⋯N hydrogen-bond interactions. |
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