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[Diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(II)

In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyl­dipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordi...

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Detalles Bibliográficos
Autores principales: Shaw, Janet L., Noll, Bruce C.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979699/
https://www.ncbi.nlm.nih.gov/pubmed/21579621
http://dx.doi.org/10.1107/S1600536810000565
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author Shaw, Janet L.
Noll, Bruce C.
author_facet Shaw, Janet L.
Noll, Bruce C.
author_sort Shaw, Janet L.
collection PubMed
description In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyl­dipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordination at the Co(II) center is best described as distorted octa­hedral with two NO(3) (−) anions serving as bidentate ligands for charge balance. The dihedral angle between the mean planes of the two nitrate rings is 85.0 (1)° and that between the mean planes of the two phenyl rings is 73.7 (1)°. The crystal structure is stabilized by weak inter­molecular C—H⋯O and intra­molecular C—H⋯N hydrogen-bond inter­actions.
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spelling pubmed-29796992010-12-30 [Diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(II) Shaw, Janet L. Noll, Bruce C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyl­dipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordination at the Co(II) center is best described as distorted octa­hedral with two NO(3) (−) anions serving as bidentate ligands for charge balance. The dihedral angle between the mean planes of the two nitrate rings is 85.0 (1)° and that between the mean planes of the two phenyl rings is 73.7 (1)°. The crystal structure is stabilized by weak inter­molecular C—H⋯O and intra­molecular C—H⋯N hydrogen-bond inter­actions. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979699/ /pubmed/21579621 http://dx.doi.org/10.1107/S1600536810000565 Text en © Shaw and Noll 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shaw, Janet L.
Noll, Bruce C.
[Diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(II)
title [Diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(II)
title_full [Diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(II)
title_fullStr [Diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(II)
title_full_unstemmed [Diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(II)
title_short [Diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(II)
title_sort [diphenyldi(pyrazol-1-yl)methane]­dinitratocobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979699/
https://www.ncbi.nlm.nih.gov/pubmed/21579621
http://dx.doi.org/10.1107/S1600536810000565
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