Cargando…
[Diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(II)
In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyldipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordi...
Autores principales: | , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979699/ https://www.ncbi.nlm.nih.gov/pubmed/21579621 http://dx.doi.org/10.1107/S1600536810000565 |
_version_ | 1782191477191868416 |
---|---|
author | Shaw, Janet L. Noll, Bruce C. |
author_facet | Shaw, Janet L. Noll, Bruce C. |
author_sort | Shaw, Janet L. |
collection | PubMed |
description | In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyldipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordination at the Co(II) center is best described as distorted octahedral with two NO(3) (−) anions serving as bidentate ligands for charge balance. The dihedral angle between the mean planes of the two nitrate rings is 85.0 (1)° and that between the mean planes of the two phenyl rings is 73.7 (1)°. The crystal structure is stabilized by weak intermolecular C—H⋯O and intramolecular C—H⋯N hydrogen-bond interactions. |
format | Text |
id | pubmed-2979699 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29796992010-12-30 [Diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(II) Shaw, Janet L. Noll, Bruce C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NO(3))(2)(C(19)H(16)N(4))], the diphenyldipyrazolylmethane ligand coordinates to Co(II) in a bidentate fashion forming a six-membered ring with an approximate boat configuration. The mean planes of the two pyrazolyl rings are separated by an angle of 39.6 (2)°. The coordination at the Co(II) center is best described as distorted octahedral with two NO(3) (−) anions serving as bidentate ligands for charge balance. The dihedral angle between the mean planes of the two nitrate rings is 85.0 (1)° and that between the mean planes of the two phenyl rings is 73.7 (1)°. The crystal structure is stabilized by weak intermolecular C—H⋯O and intramolecular C—H⋯N hydrogen-bond interactions. International Union of Crystallography 2010-01-13 /pmc/articles/PMC2979699/ /pubmed/21579621 http://dx.doi.org/10.1107/S1600536810000565 Text en © Shaw and Noll 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Shaw, Janet L. Noll, Bruce C. [Diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(II) |
title | [Diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(II) |
title_full | [Diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(II) |
title_fullStr | [Diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(II) |
title_full_unstemmed | [Diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(II) |
title_short | [Diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(II) |
title_sort | [diphenyldi(pyrazol-1-yl)methane]dinitratocobalt(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979699/ https://www.ncbi.nlm.nih.gov/pubmed/21579621 http://dx.doi.org/10.1107/S1600536810000565 |
work_keys_str_mv | AT shawjanetl diphenyldipyrazol1ylmethanedinitratocobaltii AT nollbrucec diphenyldipyrazol1ylmethanedinitratocobaltii |