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(2,2′-Bipyridine-κ(2) N,N′)bis(4-hydroxybenzoato-κ(2) O,O′)lead(II) monohydrate
The reaction of lead acetate, 4-hydroxybenzoic acid and 2,2′-bipyridine in aqueous solution gave the title complex, [Pb(C(7)H(5)O(3))(2)(C(10)H(8)N(2))]·H(2)O. The asymmetric unit contains one Pb(II) atom, two 4-hydroxybenzoate ligands, one 2,2′-bipyridine ligand and one uncoordinated water molec...
Autores principales: | , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979701/ https://www.ncbi.nlm.nih.gov/pubmed/21579690 http://dx.doi.org/10.1107/S1600536810002941 |
Sumario: | The reaction of lead acetate, 4-hydroxybenzoic acid and 2,2′-bipyridine in aqueous solution gave the title complex, [Pb(C(7)H(5)O(3))(2)(C(10)H(8)N(2))]·H(2)O. The asymmetric unit contains one Pb(II) atom, two 4-hydroxybenzoate ligands, one 2,2′-bipyridine ligand and one uncoordinated water molecule. The Pb(II) atom is hexacoordinated in a distorted tetragonal-bipyramidal geometry and is chelated by four carboxylate O atoms and two N atoms. O—H⋯O hydrogen-bonding interactions, involving the uncoordinated water, the carboxylate O atoms and hydroxy O atoms, produce a three-dimensional supramolecular structure. |
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