(2,2′-Bipyridine-κ(2) N,N′)bis­(4-hydroxy­benzoato-κ(2) O,O′)lead(II) monohydrate

The reaction of lead acetate, 4-hydroxy­benzoic acid and 2,2′-bipyridine in aqueous solution gave the title complex, [Pb(C(7)H(5)O(3))(2)(C(10)H(8)N(2))]·H(2)O. The asymmetric unit contains one Pb(II) atom, two 4-hydroxy­benzoate ligands, one 2,2′-bipyridine ligand and one uncoordinated water mol­ec...

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Detalles Bibliográficos
Autores principales: Dai, Jun, Yang, Juan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979701/
https://www.ncbi.nlm.nih.gov/pubmed/21579690
http://dx.doi.org/10.1107/S1600536810002941
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author Dai, Jun
Yang, Juan
author_facet Dai, Jun
Yang, Juan
author_sort Dai, Jun
collection PubMed
description The reaction of lead acetate, 4-hydroxy­benzoic acid and 2,2′-bipyridine in aqueous solution gave the title complex, [Pb(C(7)H(5)O(3))(2)(C(10)H(8)N(2))]·H(2)O. The asymmetric unit contains one Pb(II) atom, two 4-hydroxy­benzoate ligands, one 2,2′-bipyridine ligand and one uncoordinated water mol­ecule. The Pb(II) atom is hexa­coordinated in a distorted tetra­gonal-bipyramidal geometry and is chelated by four carboxyl­ate O atoms and two N atoms. O—H⋯O hydrogen-bonding inter­actions, involving the uncoordinated water, the carboxyl­ate O atoms and hydr­oxy O atoms, produce a three-dimensional supra­molecular structure.
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spelling pubmed-29797012010-12-30 (2,2′-Bipyridine-κ(2) N,N′)bis­(4-hydroxy­benzoato-κ(2) O,O′)lead(II) monohydrate Dai, Jun Yang, Juan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The reaction of lead acetate, 4-hydroxy­benzoic acid and 2,2′-bipyridine in aqueous solution gave the title complex, [Pb(C(7)H(5)O(3))(2)(C(10)H(8)N(2))]·H(2)O. The asymmetric unit contains one Pb(II) atom, two 4-hydroxy­benzoate ligands, one 2,2′-bipyridine ligand and one uncoordinated water mol­ecule. The Pb(II) atom is hexa­coordinated in a distorted tetra­gonal-bipyramidal geometry and is chelated by four carboxyl­ate O atoms and two N atoms. O—H⋯O hydrogen-bonding inter­actions, involving the uncoordinated water, the carboxyl­ate O atoms and hydr­oxy O atoms, produce a three-dimensional supra­molecular structure. International Union of Crystallography 2010-01-30 /pmc/articles/PMC2979701/ /pubmed/21579690 http://dx.doi.org/10.1107/S1600536810002941 Text en © Dai and Yang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Dai, Jun
Yang, Juan
(2,2′-Bipyridine-κ(2) N,N′)bis­(4-hydroxy­benzoato-κ(2) O,O′)lead(II) monohydrate
title (2,2′-Bipyridine-κ(2) N,N′)bis­(4-hydroxy­benzoato-κ(2) O,O′)lead(II) monohydrate
title_full (2,2′-Bipyridine-κ(2) N,N′)bis­(4-hydroxy­benzoato-κ(2) O,O′)lead(II) monohydrate
title_fullStr (2,2′-Bipyridine-κ(2) N,N′)bis­(4-hydroxy­benzoato-κ(2) O,O′)lead(II) monohydrate
title_full_unstemmed (2,2′-Bipyridine-κ(2) N,N′)bis­(4-hydroxy­benzoato-κ(2) O,O′)lead(II) monohydrate
title_short (2,2′-Bipyridine-κ(2) N,N′)bis­(4-hydroxy­benzoato-κ(2) O,O′)lead(II) monohydrate
title_sort (2,2′-bipyridine-κ(2) n,n′)bis­(4-hydroxy­benzoato-κ(2) o,o′)lead(ii) monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979701/
https://www.ncbi.nlm.nih.gov/pubmed/21579690
http://dx.doi.org/10.1107/S1600536810002941
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AT yangjuan 22bipyridinek2nnbis4hydroxybenzoatok2ooleadiimonohydrate

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