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catena-Poly[[[diaqua­copper(II)]-bis­(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis­(hydrogen phthalate) monohydrate]

The asymmetric unit of the title compound, {[Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)](C(8)H(5)O(4))(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water mol­ecules, two hydrogen phthalate anions and one uncoordinated wat...

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Detalles Bibliográficos
Autores principales: Zhu, Hong-Lin, Zhang, Jie, Lin, Jian-Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979707/
https://www.ncbi.nlm.nih.gov/pubmed/21579653
http://dx.doi.org/10.1107/S1600536810001716
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author Zhu, Hong-Lin
Zhang, Jie
Lin, Jian-Li
author_facet Zhu, Hong-Lin
Zhang, Jie
Lin, Jian-Li
author_sort Zhu, Hong-Lin
collection PubMed
description The asymmetric unit of the title compound, {[Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)](C(8)H(5)O(4))(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water mol­ecules, two hydrogen phthalate anions and one uncoordinated water mol­ecule. The polymeric structure consists of two types of polymeric chains, each composed from repeated chiral rhomboids. The Cu(II) ions adopt a distorted octa­hedral coordination geometry and are coordinated by four pyridine N atoms and two water O atoms. The coordinated water mol­ecules and hydrogen phthalate anions are located between the repeated rhomboidal chains, and form hydrogen bonds with the coordinated water mol­ecules.
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spelling pubmed-29797072010-12-30 catena-Poly[[[diaqua­copper(II)]-bis­(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis­(hydrogen phthalate) monohydrate] Zhu, Hong-Lin Zhang, Jie Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)](C(8)H(5)O(4))(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water mol­ecules, two hydrogen phthalate anions and one uncoordinated water mol­ecule. The polymeric structure consists of two types of polymeric chains, each composed from repeated chiral rhomboids. The Cu(II) ions adopt a distorted octa­hedral coordination geometry and are coordinated by four pyridine N atoms and two water O atoms. The coordinated water mol­ecules and hydrogen phthalate anions are located between the repeated rhomboidal chains, and form hydrogen bonds with the coordinated water mol­ecules. International Union of Crystallography 2010-01-20 /pmc/articles/PMC2979707/ /pubmed/21579653 http://dx.doi.org/10.1107/S1600536810001716 Text en © Zhu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Hong-Lin
Zhang, Jie
Lin, Jian-Li
catena-Poly[[[diaqua­copper(II)]-bis­(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis­(hydrogen phthalate) monohydrate]
title catena-Poly[[[diaqua­copper(II)]-bis­(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis­(hydrogen phthalate) monohydrate]
title_full catena-Poly[[[diaqua­copper(II)]-bis­(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis­(hydrogen phthalate) monohydrate]
title_fullStr catena-Poly[[[diaqua­copper(II)]-bis­(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis­(hydrogen phthalate) monohydrate]
title_full_unstemmed catena-Poly[[[diaqua­copper(II)]-bis­(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis­(hydrogen phthalate) monohydrate]
title_short catena-Poly[[[diaqua­copper(II)]-bis­(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis­(hydrogen phthalate) monohydrate]
title_sort catena-poly[[[diaqua­copper(ii)]-bis­(μ(2)-di-4-pyridyl disulfide-κ(2) n:n′)] bis­(hydrogen phthalate) monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979707/
https://www.ncbi.nlm.nih.gov/pubmed/21579653
http://dx.doi.org/10.1107/S1600536810001716
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