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catena-Poly[[[diaquacopper(II)]-bis(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis(hydrogen phthalate) monohydrate]
The asymmetric unit of the title compound, {[Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)](C(8)H(5)O(4))(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water molecules, two hydrogen phthalate anions and one uncoordinated wat...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979707/ https://www.ncbi.nlm.nih.gov/pubmed/21579653 http://dx.doi.org/10.1107/S1600536810001716 |
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author | Zhu, Hong-Lin Zhang, Jie Lin, Jian-Li |
author_facet | Zhu, Hong-Lin Zhang, Jie Lin, Jian-Li |
author_sort | Zhu, Hong-Lin |
collection | PubMed |
description | The asymmetric unit of the title compound, {[Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)](C(8)H(5)O(4))(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water molecules, two hydrogen phthalate anions and one uncoordinated water molecule. The polymeric structure consists of two types of polymeric chains, each composed from repeated chiral rhomboids. The Cu(II) ions adopt a distorted octahedral coordination geometry and are coordinated by four pyridine N atoms and two water O atoms. The coordinated water molecules and hydrogen phthalate anions are located between the repeated rhomboidal chains, and form hydrogen bonds with the coordinated water molecules. |
format | Text |
id | pubmed-2979707 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29797072010-12-30 catena-Poly[[[diaquacopper(II)]-bis(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis(hydrogen phthalate) monohydrate] Zhu, Hong-Lin Zhang, Jie Lin, Jian-Li Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Cu(C(10)H(8)N(2)S(2))(2)(H(2)O)(2)](C(8)H(5)O(4))(2)·H(2)O}(n), contains one Cu(II) ion, two bridging di-4-pyridyl disulfide (4-DPDS) ligands of the same chirality, two coordinating water molecules, two hydrogen phthalate anions and one uncoordinated water molecule. The polymeric structure consists of two types of polymeric chains, each composed from repeated chiral rhomboids. The Cu(II) ions adopt a distorted octahedral coordination geometry and are coordinated by four pyridine N atoms and two water O atoms. The coordinated water molecules and hydrogen phthalate anions are located between the repeated rhomboidal chains, and form hydrogen bonds with the coordinated water molecules. International Union of Crystallography 2010-01-20 /pmc/articles/PMC2979707/ /pubmed/21579653 http://dx.doi.org/10.1107/S1600536810001716 Text en © Zhu et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Hong-Lin Zhang, Jie Lin, Jian-Li catena-Poly[[[diaquacopper(II)]-bis(μ(2)-di-4-pyridyl disulfide-κ(2) N:N′)] bis(hydrogen phthalate) monohydrate] |
title |
catena-Poly[[[diaquacopper(II)]-bis(μ(2)-di-4-pyridyl disulfide-κ(2)
N:N′)] bis(hydrogen phthalate) monohydrate] |
title_full |
catena-Poly[[[diaquacopper(II)]-bis(μ(2)-di-4-pyridyl disulfide-κ(2)
N:N′)] bis(hydrogen phthalate) monohydrate] |
title_fullStr |
catena-Poly[[[diaquacopper(II)]-bis(μ(2)-di-4-pyridyl disulfide-κ(2)
N:N′)] bis(hydrogen phthalate) monohydrate] |
title_full_unstemmed |
catena-Poly[[[diaquacopper(II)]-bis(μ(2)-di-4-pyridyl disulfide-κ(2)
N:N′)] bis(hydrogen phthalate) monohydrate] |
title_short |
catena-Poly[[[diaquacopper(II)]-bis(μ(2)-di-4-pyridyl disulfide-κ(2)
N:N′)] bis(hydrogen phthalate) monohydrate] |
title_sort | catena-poly[[[diaquacopper(ii)]-bis(μ(2)-di-4-pyridyl disulfide-κ(2)
n:n′)] bis(hydrogen phthalate) monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979707/ https://www.ncbi.nlm.nih.gov/pubmed/21579653 http://dx.doi.org/10.1107/S1600536810001716 |
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