Bis{2-eth­oxy-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}dithio­cyanato­nickel(II)

In the mononuclear title complex, [Ni(NCS)(2)(C(14)H(22)N(2)O(2))(2)], the Ni atom lies on an inversion centre. It is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands, and is also coordinated by the N atoms from two thio­cyanate ligands, giving a slightly disto...

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Detalles Bibliográficos
Autores principales: Wang, Chen-Yi, Ye, Jin-Yun, Wu, Xiang, Yuan, Cai-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979711/
https://www.ncbi.nlm.nih.gov/pubmed/21579605
http://dx.doi.org/10.1107/S1600536809055780
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author Wang, Chen-Yi
Ye, Jin-Yun
Wu, Xiang
Yuan, Cai-Jun
author_facet Wang, Chen-Yi
Ye, Jin-Yun
Wu, Xiang
Yuan, Cai-Jun
author_sort Wang, Chen-Yi
collection PubMed
description In the mononuclear title complex, [Ni(NCS)(2)(C(14)H(22)N(2)O(2))(2)], the Ni atom lies on an inversion centre. It is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands, and is also coordinated by the N atoms from two thio­cyanate ligands, giving a slightly distorted octa­hedral geometry. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds are observed.
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spelling pubmed-29797112010-12-30 Bis{2-eth­oxy-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}dithio­cyanato­nickel(II) Wang, Chen-Yi Ye, Jin-Yun Wu, Xiang Yuan, Cai-Jun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the mononuclear title complex, [Ni(NCS)(2)(C(14)H(22)N(2)O(2))(2)], the Ni atom lies on an inversion centre. It is chelated by the phenolate O and imine N atoms from two zwitterionic Schiff base ligands, and is also coordinated by the N atoms from two thio­cyanate ligands, giving a slightly distorted octa­hedral geometry. Intra­molecular N—H⋯O and N—H⋯N hydrogen bonds are observed. International Union of Crystallography 2010-01-09 /pmc/articles/PMC2979711/ /pubmed/21579605 http://dx.doi.org/10.1107/S1600536809055780 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chen-Yi
Ye, Jin-Yun
Wu, Xiang
Yuan, Cai-Jun
Bis{2-eth­oxy-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}dithio­cyanato­nickel(II)
title Bis{2-eth­oxy-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}dithio­cyanato­nickel(II)
title_full Bis{2-eth­oxy-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}dithio­cyanato­nickel(II)
title_fullStr Bis{2-eth­oxy-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}dithio­cyanato­nickel(II)
title_full_unstemmed Bis{2-eth­oxy-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}dithio­cyanato­nickel(II)
title_short Bis{2-eth­oxy-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}dithio­cyanato­nickel(II)
title_sort bis{2-eth­oxy-6-[2-(isopropyl­ammonio)ethyl­imino­meth­yl]phenolato}dithio­cyanato­nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979711/
https://www.ncbi.nlm.nih.gov/pubmed/21579605
http://dx.doi.org/10.1107/S1600536809055780
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AT yejinyun bis2ethoxy62isopropylammonioethyliminomethylphenolatodithiocyanatonickelii
AT wuxiang bis2ethoxy62isopropylammonioethyliminomethylphenolatodithiocyanatonickelii
AT yuancaijun bis2ethoxy62isopropylammonioethyliminomethylphenolatodithiocyanatonickelii

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