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(R)-2′-Benzyloxy-5,5′,6,6′,7,7′,8,8′-octahydro-1,1′-binaphthyl-2-ol
The molecules of the title compound, C(27)H(28)O(2), exhibit axial chirality. The planes of the aromatic rings of the tetralin ring systems make an angle of 85.72 (11)°. The non-aromatic rings adopt distorted half-chair conformations. In one of them, two C atoms of the four-atom aliphatic chain ar...
| Autores principales: | , , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2979715/ https://www.ncbi.nlm.nih.gov/pubmed/21579852 http://dx.doi.org/10.1107/S1600536810002308 |
| Sumario: | The molecules of the title compound, C(27)H(28)O(2), exhibit axial chirality. The planes of the aromatic rings of the tetralin ring systems make an angle of 85.72 (11)°. The non-aromatic rings adopt distorted half-chair conformations. In one of them, two C atoms of the four-atom aliphatic chain are disordered over two sites in a 0.75 (2):0.25 (2) ratio. The substituent phenyl ring is also disordered over two positions in a 0.59 (3):0.41 (3) ratio. There are no conventional hydrogen bonds joining the molecules. |
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